481718
五羰基铁
>99.99% trace metals basis
别名:
五羰基铁, 羰基铁
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关于此项目
线性分子式:
Fe(CO)5
化学文摘社编号:
分子量:
195.90
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
EC Number:
236-670-8
MDL number:
vapor density
6.74 (vs air)
Quality Segment
vapor pressure
35 mmHg ( 25 °C), 40 mmHg ( 30.3 °C)
assay
>99.99% trace metals basis
form
liquid
autoignition temp.
122 °F
reaction suitability
core: iron, reagent type: catalyst
greener alternative product characteristics
Catalysis
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sustainability
Greener Alternative Product
refractive index
n20/D 1.5196 (lit.)
bp
103 °C (lit.)
mp
−20 °C (lit.)
density
1.49 g/mL at 25 °C (lit.)
greener alternative category
, Aligned
storage temp.
2-8°C
SMILES string
[Fe].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
InChI
1S/5CO.Fe/c5*1-2;
InChI key
FYOFOKCECDGJBF-UHFFFAOYSA-N
General description
Iron(0) pentacarbonyl is a straw-yellow to brilliant orange liquid soluble in organic solvents. It is widely used as a precursor for synthesizing iron oxide nanoparticles, which have applications in the field of energy conversion and storage due to their catalytic properties and ability to enhance electron transport.
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Application
用作以下过程的反应物：
- 加成反应
- 通过光解分解
- 热分解法制备尺寸分布窄的铁洋葱状富勒烯磁性微粒
- 碳酰胺氢硅烷还原反应中七核铁羰基簇合物的制备
- 高碱性条件下制备光催化析氢 Fe 纳米粒子的前驱体
Iron(0) pentacarbonyl can be used:
- To fabricate Fe-based anode materials for high-performance aqueous secondary Ni−Fe batteries. It helps to achieve good safety, high power density, long term-life cycle, and high energy density.
- As a precursor to synthesize highly stable, colloidal magnetic iron nanoparticles with narrow size distribution. These nanoparticles are potential candidates for MRI contrasting agents and magnetically separable catalysts.
- To synthesize zero valent sustainable iron nanocatalysts for reduction reactions.
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Danger
hcodes
Hazard Classifications
Acute Tox. 1 Inhalation - Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Flam. Liq. 2
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
5.0 °F - closed cup
flash_point_c
-15 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter