520772
氯化铑(III) 水合物
≥99.9% trace metals basis, crystalline
别名:
三氯化铑水合物
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关于此项目
线性分子式:
RhCl3 · xH2O
化学文摘社编号:
分子量:
209.26 (anhydrous basis)
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
233-165-4
MDL number:
产品名称
氯化铑(III) 水合物, crystalline, ≥99.9% trace metals basis
Quality Level
assay
≥99.9% trace metals basis
form
crystalline
composition
Rh, 38-43.5%
reaction suitability
core: rhodium, reagent type: catalyst
mp
100 °C (dec.) (lit.)
SMILES string
O.Cl[Rh](Cl)Cl
InChI
1S/3ClH.H2O.Rh/h3*1H;1H2;/q;;;;+3/p-3
InChI key
HSSMNYDDDSNUKH-UHFFFAOYSA-K
Application
氯化铑（III）水合物 (RhCl3. xH2O) 可用作制备以下物质的金属前体：
- 用于费托−(FT) 合成的二氧化硅负载铑-钴 (Rh-Co) 催化剂（双金属催化剂）
- 用于酮的不对称还原的铑 (III) 催化剂，N-2-(2,3,4,5 四甲基l环戊二烯基)苄基-(l)-去甲基麻黄碱氯化铑 (III)
- 用于1-辛烯的加氢甲酰化的Rh@CTF（共价三嗪骨架）催化剂
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signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Muta. 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
存储类别
11 - Combustible Solids
A new class of Rh (III) catalyst containing an aminoalcohol tethered to a tetramethylcyclopentadienyl group for asymmetric transfer hydrogenation of ketones
Cross DJ, et al.
Tetrahedron Letters, 45(4), 843-846 (2004)
Silica-supported rhodium-cobalt catalysts for Fischer-Tropsch synthesis
Yan Z, et al.
Catalysis Today, 160(1), 39-43 (2011)
N-containing covalent organic frameworks as supports for rhodium as transition-metal catalysts in hydroformylation reactions
Pilaski M, et al.
Microporous and Mesoporous Materials : The Official Journal of the International Zeolite Association, 227(4), 219-227 (2016)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 520772-1G | 04061832547084 |
| 520772-5G | 04061832547091 |