640360
双（乙腈）（1,5-环辛二烯）铑 (I) 四氟硼酸盐
solid
别名:
[Rh(cod)(MeCN)2]BF4
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选择尺寸
关于此项目
经验公式（希尔记法）:
C12H18BF4N2Rh
化学文摘社编号:
分子量:
379.99
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
双（乙腈）（1,5-环辛二烯）铑 (I) 四氟硼酸盐,
SMILES string
[Rh+].CC#N.CC#N.F[B-](F)(F)F.C1CC=CCCC=C1
InChI
1S/C8H12.2C2H3N.BF4.Rh/c1-2-4-6-8-7-5-3-1;2*1-2-3;2-1(3,4)5;/h1-2,7-8H,3-6H2;2*1H3;;/q;;;-1;+1/b2-1-,8-7-;;;;
InChI key
KSMAFOANQHYEJG-SUESZSCISA-N
form
solid
reaction suitability
core: rhodium
reagent type: catalyst
Quality Level
Application
双（乙腈）（1,5-环辛二烯）四氟硼酸铑（I）[Rh(cod)(MeCN)2]BF4 可作为催化剂用于芳基碘和溴与四乙氧基硅烷的铑（I）催化甲硅烷基化反应 以形成芳基硅烷，例如（4-溴苯基）三乙氧基硅烷和4-（三乙氧基甲硅烷基）苯乙酮。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Pingping Tang et al.
Tetrahedron, 67(24), 4449-4454 (2011-06-22)
A regiospecific silver-mediated fluorination of aryl silanes is reported. The reaction is operationally simple, and employs Ag(2)O as readily available, inexpensive silver source, which can be recovered.
Periodic mesoporous organosilica containing ionic bis-aryl-imidazolium entities: Heterogeneous precursors for silica-hybrid-supported NHC complexes.
Nguyen TP, et al.
Journal of Materials Chemistry, 19(24), 4164-4171 (2009)
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