667412
五甲基环戊二烯基三（乙腈）钌 (II) 六氟磷酸盐
solid
别名:
[RuCp*(MeCN)3]PF6
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关于此项目
经验公式（希尔记法）:
C16H24N3PRuF6
化学文摘社编号:
分子量:
504.42
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
五甲基环戊二烯基三（乙腈）钌 (II) 六氟磷酸盐,
form
solid
Quality Level
reaction suitability
core: ruthenium, reagent type: catalyst
greener alternative product characteristics
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
greener alternative category
storage temp.
2-8°C
SMILES string
[Ru+].CC#N.CC#N.CC#N.F[P-](F)(F)(F)(F)F.CC1C(C)=C(C)C(C)=C1C
InChI
1S/C10H16.3C2H3N.F6P.Ru/c1-6-7(2)9(4)10(5)8(6)3;3*1-2-3;1-7(2,3,4,5)6;/h6H,1-5H3;3*1H3;;/q;;;;-1;+1
InChI key
IYEMDYLFXFMECZ-UHFFFAOYSA-N
General description
We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This product falls under category 12 PAP and aligns with the Green Chemistry Principle of Catalysis. It is a precursor for pentamethylcyclopentadienyl rhodium complexes used in coordination chemistry and catalysis providing enhanced stability and solubility. Click here for more information.
五甲基环戊二烯基三(乙腈)六氟磷酸钌(II)是一种有机钌化合物。它在有机合成中用作均相催化剂。它能够实现炔烃氢化硅烷化、炔烃环三聚化、环加成和碳-碳或碳-杂原子成键反应。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
商品
Trost group's protocol yields α-vinylsilanes from terminal acetylenes using [Cp*Ru(MeCN)3]PF6 catalyst and others for hydrosilylation.
Markovnikov alkyne hydrosilylation catalyzed by ruthenium complexes.
B M Trost et al.
Journal of the American Chemical Society, 123(50), 12726-12727 (2001-12-14)
Barry M Trost et al.
Journal of the American Chemical Society, 127(50), 17644-17655 (2005-12-15)
The complex [Cp*Ru(MeCN)3]PF6 is shown to catalyze the hydrosilylation of a wide range of alkynes. Terminal alkynes afford access to alpha-vinylsilane products with good regioselectivity. Deuterium labeling studies indicate a clean trans addition process is at work. The same complex
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 667412-250MG | 04061833483664 |