679011
2-(二苯基膦)对苯二甲酸 1-甲基 4-五氟苯基二酯
97%
别名:
1-甲基-4-(五氟苯基)-2-(二苯基膦)-1,4-苯二羧酸酯
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About This Item
经验公式（希尔记法）:
C27H16F5O4P
CAS Number:
分子量:
530.38
MDL编号:
UNSPSC代码:
12352106
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
97%
表单
solid
反应适用性
reaction type: click chemistry
mp
109-111 °C
储存温度
−20°C
SMILES字符串
COC(=O)c1ccc(cc1P(c2ccccc2)c3ccccc3)C(=O)Oc4c(F)c(F)c(F)c(F)c4F
InChI
1S/C27H16F5O4P/c1-35-27(34)18-13-12-15(26(33)36-25-23(31)21(29)20(28)22(30)24(25)32)14-19(18)37(16-8-4-2-5-9-16)17-10-6-3-7-11-17/h2-14H,1H3
InChI key
OURNVXDJALDDIG-UHFFFAOYSA-N
应用
- Staudinger ligation reagent for the conjugation of amine and azide containing compounds or biomolecules.
- The amine functionalized molecule first reacts with the phosphine through the activated pentafluorophenyl ester.The azide-molecule is then reacted with the newly labeled phosphine to form the iminophosphorane, and the aza-ylide is subsequently captured by the methyl ester to yield the covalent conjugated product.
The Staudinger Ligation: A High-Yield, Chemoselective, and Mild Synthetic Method
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
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