683175
Chiralyst P374
solid, Umicore
别名:
双（降冰片二烯）铑 (I) 四氟硼酸盐, [Rh(nbd)Cl]4, 双（双环[2.2.1]庚-2,5-二烯）四氟硼酸铑, 双（降冰片二烯）（四氟硼酸）铑, Rh(nbd)2BF4
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关于此项目
线性分子式:
[Rh(NBD)BF4
化学文摘社编号:
分子量:
373.99
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
Chiralyst P374, Umicore
SMILES string
[Rh+].F[B-](F)(F)F.C1C2C=CC1C=C2.C3C4C=CC3C=C4
InChI
1S/2C7H8.BF4.Rh/c2*1-2-7-4-3-6(1)5-7;2-1(3,4)5;/h2*1-4,6-7H,5H2;;/q;;-1;+1/t2*6-,7+;;
InChI key
HAYDJWBQWOEERB-JAGGYEKFSA-N
form
solid
reaction suitability
core: rhodium, reagent type: catalyst
mp
136.9-139.9 °C
Quality Level
Application
双（降冰片二烯）铑(I) 四氟硼酸可用作催化剂来合成以下物质：
- 通过芳基硼酸的1,4加成形成丁烯羟酸内酯
- 手性β芳基取代的酮和酯。
- β-由 β-芳氧基α,γ-不饱和酯形成芳氧基碳酸酯。
Legal Information
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Enantioselective Synthesis of ?-Aryloxycarboxylic Esters via Asymmetric Hydrogenation of ?-Aryloxy-?, ?-Unsaturated Esters
Stewart GW, et al.
Organic Letters, 14(21), 5440-5443 (2012)
Determination of the absolute configuration of two ?v?6 integrin inhibitors for the treatment of idiopathic pulmonary fibrosis and investigations on the asymmetric 1, 4-addition of arylboronic acids to crotonate esters bearing a C4-oxygen substituent
Procopiou PA, et al.
Tetrahedron Asymmetry, 28(10), 1384-1393 (2017)
Practical method for asymmetric addition of arylboronic acids to ?, ?-unsaturated carbonyl compounds utilizing an in situ prepared rhodium catalyst
Lukin K, et al.
The Journal of Organic Chemistry, 74(2), 929-931 (2008)
商品
Precatalysts for asymmetric catalysis offer batch-to-batch consistency in a range of catalytic reactions, supporting diverse research needs.
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