683175
Chiralyst P374
solid, Umicore
别名:
双（降冰片二烯）铑 (I) 四氟硼酸盐, [Rh(nbd)Cl]4, 双（双环[2.2.1]庚-2,5-二烯）四氟硼酸铑, 双（降冰片二烯）（四氟硼酸）铑, Rh(nbd)2BF4
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关于此项目
线性分子式:
[Rh(NBD)BF4
化学文摘社编号:
分子量:
373.99
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
Chiralyst P374, Umicore
SMILES string
[Rh+].F[B-](F)(F)F.C1C2C=CC1C=C2.C3C4C=CC3C=C4
InChI
1S/2C7H8.BF4.Rh/c2*1-2-7-4-3-6(1)5-7;2-1(3,4)5;/h2*1-4,6-7H,5H2;;/q;;-1;+1/t2*6-,7+;;
InChI key
HAYDJWBQWOEERB-JAGGYEKFSA-N
form
solid
reaction suitability
core: rhodium
reagent type: catalyst
mp
136.9-139.9 °C
Quality Level
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Application
双（降冰片二烯）铑(I) 四氟硼酸可用作催化剂来合成以下物质：
- 通过芳基硼酸的1,4加成形成丁烯羟酸内酯
- 手性β芳基取代的酮和酯。
- β-由 β-芳氧基α,γ-不饱和酯形成芳氧基碳酸酯。
Legal Information
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Determination of the absolute configuration of two ?v?6 integrin inhibitors for the treatment of idiopathic pulmonary fibrosis and investigations on the asymmetric 1, 4-addition of arylboronic acids to crotonate esters bearing a C4-oxygen substituent
Procopiou PA, et al.
Tetrahedron Asymmetry, 28(10), 1384-1393 (2017)
Enantioselective Synthesis of ?-Aryloxycarboxylic Esters via Asymmetric Hydrogenation of ?-Aryloxy-?, ?-Unsaturated Esters
Stewart GW, et al.
Organic Letters, 14(21), 5440-5443 (2012)
Practical method for asymmetric addition of arylboronic acids to ?, ?-unsaturated carbonyl compounds utilizing an in situ prepared rhodium catalyst
Lukin K, et al.
The Journal of Organic Chemistry, 74(2), 929-931 (2008)
商品
Precatalysts for asymmetric catalysis offer batch-to-batch consistency in a range of catalytic reactions, supporting diverse research needs.
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