Name: 双(1,5-环辛二烯)四[双(3,5-三氟甲基)苯基]硼酸铑(I)
Brand: ALDRICH

登录查看公司和协议定价

About This Item

经验公式（希尔记法）:

C₄₈H₃₆BF₂₄Rh

CAS Number:

404573-66-6

分子量:

1182.48

MDL编号:

MFCD10567026

UNSPSC代码:

12161600

PubChem化学物质编号:

329761509

NACRES:

NA.22

技术服务

需要帮助？我们经验丰富的科学家团队随时乐意为您服务。

让我们为您提供帮助

Product Name

双(1,5-环辛二烯)四[双(3,5-三氟甲基)苯基]硼酸铑(I),

表单

solid

反应适用性

core: rhodium
reagent type: catalyst

mp

155-156 °C (D)

储存温度

−20°C

SMILES字符串

[Rh+].C1CC=CCCC=C1.C2CC=CCCC=C2.FC(F)(F)c3cc(cc(c3)C(F)(F)F)[B-](c4cc(cc(c4)C(F)(F)F)C(F)(F)F)(c5cc(cc(c5)C(F)(F)F)C(F)(F)F)c6cc(cc(c6)C(F)(F)F)C(F)(F)F

InChI

1S/C32H12BF24.2C8H12.Rh/c34-25(35,36)13-1-14(26(37,38)39)6-21(5-13)33(22-7-15(27(40,41)42)2-16(8-22)28(43,44)45,23-9-17(29(46,47)48)3-18(10-23)30(49,50)51)24-11-19(31(52,53)54)4-20(12-24)32(55,56)57;2*1-2-4-6-8-7-5-3-1;/h1-12H;2*1-2,7-8H,3-6H2;/q-1;;;+1/b;2*2-1-,8-7-;

InChI key

HQQAEXNVAYMZON-AUUWQFPRSA-N

应用

Bis(1,5-cyclooctadiene)rhodium(I) tetrakis[bis(3,5-trifluoromethyl)phenyl]borate can be used as a catalyst for various transformations, including hydrogenation, intramolecular C-H alkenylation, cycloaddition of enynes, and reductive coupling reactions.