701211
乙酰丙酮酰双(亚乙基)化铑(I)
95%, solid
别名:
Bis(η2-ethene)(2,4-pentanedionato-κO,κO′)-rhodium, Bis(ethylene)rhodium(I) acetylacetonate, 乙酰丙酮二(乙烯)铑, 乙酰丙酮二乙烯铑配合物, 二(乙烯)乙酰丙酮铑
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关于此项目
经验公式（希尔记法）:
C9H15O2Rh
化学文摘社编号:
分子量:
258.12
EC 号:
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22
产品名称
乙酰丙酮酰双(亚乙基)化铑(I), 95%
质量水平
方案
95%
表单
solid
反应适用性
core: rhodium
reagent type: catalyst
mp
141-142 °C
储存温度
2-8°C
SMILES字符串
C=C.C=C.CC(=O)\C=C(\C)O[Rh]
InChI
1S/C5H8O2.2C2H4.Rh/c1-4(6)3-5(2)7;2*1-2;/h3,6H,1-2H3;2*1-2H2;/q;;;+1/p-1/b4-3-;;;
InChI key
FLRBEQQDEGBCJS-FGSKAQBVSA-M
一般描述
Acetylacetonatobis(ethylene)rhodium(I) is a coordination compound commonly used as a precursor to synthesize mononuclear rhodium complexes. In addition, it is also used as a catalyst in asymmetric arylation reactions.
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Rhodium-catalyzed asymmetric phenylation of N-phosphinoylarylimines with triphenylborane
Hao X, et al.
Catalysis Science & Technology, 1(1), 62-64 (2011)
Rhodium complex with ethylene ligands supported on highly dehydroxylated MgO: synthesis, characterization, and reactivity
Bhirud VA, et al.
Langmuir, 22(1), 490-496 (2006)
Chiral bicyclic bridgehead phosphoramidite (briphos) ligands for asymmetric rhodium-catalyzed 1, 2-and 1, 4-addition
Lee A, et al.
The Journal of Organic Chemistry, 81(9) , 3520-3527 (2016)
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