753009
SPho Pd G2
solid
别名:
SPhos-Pd-G2, 氯（2-二环己基膦-2′,6′-二甲氧基-1,1′-联苯）[2-（2′-氨基-1,1′-联苯）] 钯(II), 第二代 SPhos 预催化剂
选择尺寸
关于此项目
产品名称
SPho Pd G2,
SMILES string
COC1=CC=CC(OC)=C1C2=C(P(C3CCCCC3)C4CCCCC4)C=CC=C2.NC5=C(C6=C([Pd]Cl)C=CC=C6)C=CC=C5
InChI key
NOMWEFBAPVZIIP-UHFFFAOYSA-M
InChI
1S/C26H35O2P.C12H10N.ClH.Pd/c1-27-23-17-11-18-24(28-2)26(23)22-16-9-10-19-25(22)29(20-12-5-3-6-13-20)21-14-7-4-8-15-21;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;/h9-11,16-21H,3-8,12-15H2,1-2H3;1-6,8-9H,13H2;1H;/q;;;+1/p-1
Quality Level
product line
Buchwald precatalyst Generation 2
form
solid
feature
generation 2
reaction suitability
core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplings
mp
218 °C (dec.)
functional group
phosphine
General description
Application
- 1-烷基-3-溴-2-苯基-2,1-硼杂萘的自芳基化生成 2,1-硼杂萘二酚。
- Ru (bpy) 2] + 与 4-羧基苯硼酸的 Suzuki–Miyaura 偶联。
- Suzuki–Miyaura 偶联-硼化卟啉与 2-碘苯胺。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
商品
Buchwald precatalysts and ligands are bulky electron-rich dialkylbiaryl phospine-based catalysts and structurally related ligands that improve reactivity in Pd-catalyzed cross - coupling reactions
All contents in the foil bag are weighed, plated, packed, and sealed in a glove box under nitrogen.
Preformed catalysts in the kit are stable but become air-sensitive when activated; Schlenk technique aids scale-up.
Tools aid in kit setup for organic chemistry techniques, ensuring ease and success.
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