804959
DavePhos-Pd-G3
95%, solid
别名:
甲烷磺酸-2-二环己基膦基-2-(N,N-二甲胺基)联苯基(′-氨基-1,1′-联苯-2-基)钯(II)
选择尺寸
关于此项目
产品名称
DavePhos-Pd-G3, 95%
SMILES string
CN(C)C1=C(C2=C(P(C3CCCCC3)C4CCCCC4)C=CC=C2)C=CC=C1.NC5=C(C6=C([Pd]OS(C)(=O)=O)C=CC=C6)C=CC=C5
InChI key
FBIRGVXUSGLNQE-UHFFFAOYSA-M
InChI
1S/C26H36NP.C12H10N.CH4O3S.Pd/c1-27(2)25-19-11-9-17-23(25)24-18-10-12-20-26(24)28(21-13-5-3-6-14-21)22-15-7-4-8-16-22;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h9-12,17-22H,3-8,13-16H2,1-2H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1
assay
95%
form
solid
feature
generation 3
reaction suitability
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings
impurities
<5% THF
mp
183-200 °C (decomp)
functional group
phosphine
Quality Level
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Application
General description
signalword
Warning
hcodes
Hazard Classifications
Carc. 2
supp_hazards
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
商品
All contents in the foil bag are weighed, plated, packed, and sealed in a glove box under nitrogen.
G3 and G4 Buchwald palladium precatalysts are the newest air, moisture, and thermally stable crossing-coupling complexes used in bond formation for their versatility and high reactivity.
Preformed catalysts in the kit are stable but become air-sensitive when activated; Schlenk technique aids scale-up.
Preformed catalysts in the kit are stable but become air-sensitive when activated; Schlenk technique aids scale-up.
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