901755
nitro-Grela
≥95%, powder
别名:
(1,3-Dimesitylimidazolidin-2-ylidene)dichloro(2-isopropoxy-5-nitrobenzylidene)ruthenium(II)
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关于此项目
经验公式（希尔记法）:
C31H37Cl2N3O3Ru
化学文摘社编号:
分子量:
671.62
MDL number:
UNSPSC Code:
12161600
NACRES:
NA.22
产品名称
nitro-Grela, ≥95%
SMILES string
[Ru+2](=C2N(CCN2c4c(cc(cc4C)C)C)c3c(cc(cc3C)C)C)=Cc1c(ccc(c1)[N+](=O)[O-])OC(C)C.[Cl-].[Cl-]
InChI
1S/C21H26N2.C10H11NO3.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-7(2)14-10-5-4-9(11(12)13)6-8(10)3;;;/h9-12H,7-8H2,1-6H3;3-7H,1-2H3;2*1H;/q;;;;+2/p-2
InChI key
RQQSRSPQJIAORC-UHFFFAOYSA-L
assay
≥95%
form
powder
reaction suitability
core: ruthenium, reagent type: catalyst
mp
>300 °C
storage temp.
2-8°C
Application
nitro-Grela is a universal catalyst which provides good results in a wide spectrum of olefin metathesis transformations. The catalyst provides high efficiency in cross metathesis (CM) reactions between type 1 olefins and an electron deficient partner. The catalyst is very good for CM of disubstituted internal olefins.
Legal Information
Sold in collaboration with Apeiron Synthesis, Inc. Research quantities are 100 g / customer / year. For quantities that exceed the research limit, please contact the supplier at www.apeiron-synthesis.com.
PCT/EP2003/011222
PCT/EP2003/011222
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Cross-metathesis reaction of vinyl sulfones and sulfoxides.
Grela K, et al.
Tetrahedron, 59, 4525-4531 (2003)
A highly efficient ruthenium catalyst for metathesis reactions.
Karol Grela et al.
Angewandte Chemie (International ed. in English), 41(21), 4038-4040 (2002-11-02)
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