107794

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Distributed Drug Discovery, Part 2: global rehearsal of alkylating agents for the synthesis of resin-bound unnatural amino acids and virtual D(3) catalog construction.

William L Scott et al.

Journal of combinatorial chemistry, 11(1), 14-33 (2008-12-25)

Distributed Drug Discovery (D(3)) proposes solving large drug discovery problems by breaking them into smaller units for processing at multiple sites. A key component of the synthetic and computational stages of D(3) is the global rehearsal of prospective reagents and

A practical synthesis of (R)-and (S)-3-amino-3, 4-dihydro-1H-quinolin-2-one.

Hulin B and Lopaze MG.

Tetrahedron Asymmetry, 15(12), 1957-1958 (2004)

Light-regulated growth from dynamic swollen substrates for making rough surfaces.

Lulu Xue et al.

Nature communications, 11(1), 963-963 (2020-02-23)

Natural organic structures form via a growth mode in which nutrients are absorbed, transported, and integrated. In contrast, synthetic architectures are constructed through fundamentally different methods, such as assembling, molding, cutting, and printing. Here, we report a photoinduced strategy for

The Effect of the ortho Nitro Group in the Solvolysis of Benzyl and Benzoyl Halides.

Kyoung-Ho Park et al.

International journal of molecular sciences, 20(16) (2019-08-21)

A kinetic study was carried out on the solvolysis of o-nitrobenzyl bromide (o-isomer, 1) and p-nitrobenzyl bromide (p-isomer, 3), and o-nitrobenzoyl chloride (o-isomer, 2) in a wide range of solvents under various temperatures. In all of the solvents without aqueous

A photolabile hydrogel for guided three-dimensional cell growth and migration.

Ying Luo et al.

Nature materials, 3(4), 249-253 (2004-03-23)

Tissue engineering aims to replace, repair or regenerate tissue/organ function, by delivering signalling molecules and cells on a three-dimensional (3D) biomaterials scaffold that supports cell infiltration and tissue organization. To control cell behaviour and ultimately induce structural and functional tissue

Caged cysteine and thiophosphoryl peptides.

P Pan et al.

FEBS letters, 405(1), 81-85 (1997-03-17)

Photoreleasable molecules are important in studies of various biological phenomena, especially cell signaling. Here we report a generally applicable approach for 'caging' unprotected cysteine-containing or thiophosphorylated peptides in aqueous solution with 2-nitrobenzyl bromides. Photolysis of the caged peptides was achieved

Morphological Transitions of Photoresponsive Vesicles from Amphiphilic Polypeptoid Copolymers for Controlled Release.

Xu Yang et al.

Polymers, 12(4) (2020-04-09)

Photoresponsive polymers have attracted increasing interest for a variety of applications. Here, we report a family of photoresponsive polypeptoid-based copolymer poly(ethylene glycol)-b-poly(N-(S-(o-nitrobenzyl)-thioethyl) glycine)-co-poly(N-(2-phenylethyl) glycine) (PEG-b-PNSN-co-PNPE) synthesized by the controlled ring-opening polymerization (ROP) technique. The key feature of the design is

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