452114

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Catalyzed Reformatsky reactions with ethyl bromofluoroacetate for the synthesis of alpha-fluoro-beta-hydroxy acids.

R Ocampo et al.

The Journal of organic chemistry, 67(1), 72-78 (2002-01-05)

The presence of catalytic amounts of CeCl(3) improves yields and simplifies procedure in the Reformatsky reactions of ethyl bromofluoroacetate with aldehydes and ketones to generate diastereomeric mixtures of alpha-fluoro-beta-hydroxy esters, some of which can be separated by crystallization or column

Journal of the Chemical Society. Perkin Transactions 1, 49-49 (1991)

A straightforward and highly diastereoselective access to functionalized monofluorinated cyclopropanes via a Michael initiated ring closure reaction.

Thibault Ferrary et al.

Organic letters, 15(21), 5598-5601 (2013-10-22)

The synthesis of highly functionalized monofluorinated cyclopropanes based on a Michael Initiated Ring Closure (MIRC) reaction has been developed. The addition of quaternary ammonium salts derived from ethyl bromofluoroacetate on a panel of electron deficient alkenes followed by cyclization gave

Visible-light-mediated fluoroalkylation of isocyanides with ethyl bromofluoroacetates: unified synthesis of mono- and difluoromethylated phenanthridine derivatives.

Xiaoyang Sun et al.

Organic letters, 16(11), 2938-2941 (2014-05-23)

A practical and unified strategy has been described for the preparation of mono- and difluoromethylated phenanthridine derivatives using a visible-light-promoted alkylation and decarboxylation sequence from biphenyl isocyanides with ethyl bromofluoroacetate (EBFA) or ethyl bromodifluoroacetate (EBDFA). These reactions could be carried

Journal of Fluorine Chemistry, 77, 45-45 (1996)

Synthesis of (E)-and (Z)-fluoro-olefin analogues of potent dipeptidyl peptidase IV inhibitors.

Van der Veken P, et al.

Tetrahedron Letters, 44(33), 6231-6234 (2003)

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