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Photocatalysis

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facet applications:Photocatalysis
facet content type:Technical Article
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放大指南:光催化反应
光催化反应放大指南,通过高通量筛选试剂盒最大限度提高放大成功率。
可见光光氧化还原催化
自由基化学在有机合成中的应用已经过充分发展且影响广泛,但常常受制于对有毒自由基引发剂的依赖。
Photoredox Iridium Catalyst for Single Electron Transfer (SET) Cross-Coupling
Csp2- and Csp-hybridized coupling reactions are established catalytic approaches. However, multi-step Csp3- and Csp2-coupling reactions of boronic acids and related derivatives are still limited by ineffective two-electron transmetalation reactions.
Scale-Up Guide: Photocatalysis Reaction
Scale-Up Guide for Photocatalysis Reaction to best enable scale-up success with High-Throughput Screening Kit.
Single-Electron Oxidation-Induced Chemical Transformations
This review outlines the sustainable reactions occurring through the SET mechanism, leading to the formation of carbon-carbon bonds and rearrangement of oxaziridines in photoredox catalysis using newly developed neutral silicon-based radical precursors.
Recent Advances in the Catalytic Transformations
This article details the latest progress in synthesizing alkylsulfonyl fluorides through different approaches that utilize photoredox catalysis, electrocatalysis, transition-metal catalysis, and organocatalysis. The alkylsulfonyl fluorides thus prepared could be utilized further in sulfur(VI) fluoride exchange (SuFEx) click reactions.
Reducing Organic Photoredox Catalysts for Visible Light-Driven Polymer and Small Molecule Synthesis
Photoredox catalysis is a powerful synthetic methodology to form challenging covalent bonds using light irradiation. It is effective for light-driven polymer and small molecule synthesis.
Micro Photochemical Reactor
Synthetic chemists’ interest in photocatalysis has grown dramatically over the last decade, with an increasing number of leading research groups contributing innovative new methods and applications for utilizing visible light in organic synthesis.
Visible-light Photoredox Catalysis
The application of radical chemistry towards organic synthesis is well-developed and wide-reaching, though often hampered by a dependence on toxic radical initiators.
KitAlysis™ High-Throughput Photocatalysis Reaction Screening Kit
The PhotoKitAlysis Reaction Kit was designed to provide the best possible chance of finding good reaction conditions for cross-coupling reactions: pre-weighed base or base solution (provided), 10–20 mmol coupling partner (user supplied), 10 mmol aryl halide substrate (user supplied), Catalysts
Nicewicz Photoredox Catalysts for Anti-Markovnikov Alkene Hydrofunctionalization
While Markovnikov alkene reactivity is very well developed and utilized commonly in the synthesis of commodity and research chemicals, catalytic access to the anti-Markovnikov-selective adducts is a much less-developed endeavor.