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Biosynthesis of the metalloclusters of molybdenum nitrogenase.

Biosynthesis of the metalloclusters of molybdenum nitrogenase.

Microbiology and molecular biology reviews : MMBR (2011-12-01)

Yilin Hu, Markus W Ribbe

摘要

Nitrogenase catalyzes a key step in the global nitrogen cycle, the nucleotide-dependent reduction of atmospheric dinitrogen to bioavailable ammonia. There is a substantial amount of interest in elucidating the biosynthetic mechanisms of the FeMoco and the P-cluster of nitrogenase, because these clusters are not only biologically important but also chemically unprecedented. In this review, we summarize the recent advances in this research area, with an emphasis on our work that aims at providing structural and spectroscopic insights into the assembly of these complex metalloclusters.

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钼, powder, <150 μm, 99.9% trace metals basis

Sigma-Aldrich

钼, foil, thickness 0.025 mm, ≥99.9% trace metals basis

Sigma-Aldrich

钼, powder, <150 μm, 99.99% trace metals basis

Sigma-Aldrich

钼, foil, thickness 0.1 mm, ≥99.9% trace metals basis

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钼, powder, 10 μm, ≥99.95% trace metals basis

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钼, nanopowder, <100 nm particle size (TEM), 99.8% trace metals basis

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钼, wire, diam. 1.0 mm, 99.95% trace metals basis

Sigma-Aldrich

钼, foil, thickness 1.0 mm, ≥99.9% trace metals basis

钼, foil, 15mm disks, thickness 0.005mm, 99.9%

钼, mesh, 100x100mm, nominal aperture 0.44mm, wire diameter 0.07mm, 50 wires/inch, open area 67%, plain weave mesh

钼, wire, straight, 1000mm, diameter 0.5mm, 99.95%

钼, pellets, 200g, max. size 10mm, 99.9%

钼, wire reel, 1000m, diameter 0.125mm, annealed, 99.95%

钼, pellets, 100g, max. size 10mm, 99.9%

钼, rod, 50mm, diameter 5.0mm, 99.98%

钼, pellets, 50g, max. size 10mm, 99.9%

钼, mesh, 150x150mm, nominal aperture 0.44mm, wire diameter 0.07mm, 50 wires/inch, open area 67%, plain weave mesh

钼, foil, 50x50mm, thickness 0.1mm, annealed, 99.9%

钼, foil, 25mm disks, thickness 0.0125mm, 99.9%

钼, wire reel, 1000m, diameter 0.035mm, as drawn, 99.95%

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钼, wire, straight, 1000mm, diameter 0.25mm, 99.95%

钼, tube, 100mm, outside diameter 1.0mm, inside diameter 0.7mm, wall thickness 0.15mm, 99.9%

钼, foil, 100x100mm, thickness 0.1mm, annealed, 99.9%

钼, foil, 100x100mm, thickness 0.5mm, annealed, 99.9%

钼, foil, 0.5m coil, thickness 0.05mm, annealed, 99.9%

钼, rod, 150mm, diameter 5.0mm, 99.98%

钼, rod, 100mm, diameter 2.0mm, centerless ground, 99.9%

钼, wire reel, 50m, diameter 0.025mm, hard, 99.95%

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