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Merck
CN

483699

Potassium selenocyanate

ReagentPlus®, ≥99%

Synonym(s):

Selenocyanic acid potassium

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About This Item

Linear Formula:
KSeCN
CAS Number:
Molecular Weight:
144.08
UNSPSC Code:
12352302
NACRES:
NA.23
PubChem Substance ID:
EC Number:
222-320-1
Beilstein/REAXYS Number:
3912121
MDL number:
Assay:
≥99%
Form:
solid
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InChI key

KYEKHFSRAXRJBR-UHFFFAOYSA-M

InChI

1S/CHNSe.K/c2-1-3;/h3H;/q;+1/p-1

SMILES string

[K][Se]C#N

product line

ReagentPlus®

assay

≥99%

form

solid

reaction suitability

core: potassium

technique(s)

NMR: suitable

mp

147 °C

Quality Level

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Application

Increasing interest in solid state NMR of heavy-metal nuclei results in the preparation of several Hg-thiocyanate and selenocyanate compounds as potential models.

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

signalword

Danger

Hazard Classifications

Acute Tox. 2 Oral - Acute Tox. 3 Inhalation - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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Mark P de Souza et al.
Plant physiology, 128(2), 625-633 (2002-02-14)
Selenocyanate (SeCN(-)) is a major contaminant in the effluents from some oil refineries, power plants, and in mine drainage water. In this study, we determined the potential of Indian mustard (Brassica juncea) and muskgrass (a macroalga, Chara canescens) for SeCN(-)
Rajmund Mokso et al.
Physical chemistry chemical physics : PCCP, 10(28), 4138-4146 (2008-07-10)
The microwave spectra of propa-1,2-dienyl selenocyanate, H(2)C==C==CHSeC[triple bond]N, and cyclopropyl selenocyanate, C(3)H(5)SeC[triple bond]N, are reported. The spectra of the ground and two vibrationally excited states of the (80)Se isotopologue and the spectrum of the ground state of the (78)Se isotopologue
Hyewon Son et al.
The journal of physical chemistry. B, 116(30), 9152-9159 (2012-07-04)
Spectroscopic properties (i.e., peak positions and widths) of vibrational probes are sensitively dependent on their local environments in liquids. Such spectroscopic sensitivities can be utilized for studying the structures and dynamics of a variety of molecular systems. Here, we have
Denina Bobbie Dawn Simmons et al.
Environmental science & technology, 45(6), 2165-2171 (2011-02-24)
The common green fresh water algae Chlorella vulgaris was exposed to starting concentrations of 10 μg/L selenium in the form of selenate, selenite, or selenocyanate (SeCN(-)) for nine days in 10% Bold's basal medium. Uptake of selenate was more pronounced
Xiaoguang Meng et al.
Water research, 36(15), 3867-3873 (2002-10-09)
Batch experiments were conducted to investigate the removal of selenocyanate (SeCN-) from oil refinery wastewater and artificial wastewater with elemental iron [Fe(0)]. The chemical forms of selenium in the reacted solids were determined with X-ray photoelectron spectroscopy (XPS) and a

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