205036
Tris(triphenylphosphine)rhodium(I) chloride
99.9% trace metals basis
Synonym(s):
NSC 124140, RhCl(PPh3)3, Rhodium(I) tris(triphenylphosphine) chloride, Wilkinson’s catalyst
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About This Item
Linear Formula:
[(C6H5)3P]3RhCl
CAS Number:
Molecular Weight:
925.22
UNSPSC Code:
12161600
NACRES:
NA.22
PubChem Substance ID:
EC Number:
238-744-5
Beilstein/REAXYS Number:
4581440
MDL number:
Quality Segment
assay
99.9% trace metals basis
reaction suitability
core: rhodium, reagent type: catalyst
SMILES string
Cl[Rh].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9
InChI
1S/3C18H15P.ClH.Rh/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;1H;/q;;;;+1/p-1
InChI key
IXAYKDDZKIZSPV-UHFFFAOYSA-M
Application
Useful catalyst for the efficient cross-coupling of activated alkenyl tosylates with arylboronic acids. Also used to catalyze the cleavage of allyl phenolic ethers to phenols with DABCO.
Hydrosilylation Catalysts
Catalyst used for many organic reactions including:
Catalyst used for many organic reactions including:
- Chemoselective allylic alkylations
- Stoichiometric activation of Si-H bonds and hydrosilylations
- Inter- and intramolecular hydroacylation of alkenes along with a cocatalyst
- Polymerization of diorganostannanes
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hcodes
pcodes
ppe
Eyeshields, Gloves, type N95 (US)
flash_point_f
Not applicable
flash_point_c
Not applicable
Hazard Classifications
Aquatic Chronic 2
Storage Class
13 - Non Combustible Solids
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