223662
Tris(triphenylphosphine)ruthenium(II) dichloride
97%
Synonym(s):
Tris(triphenylphosphine)dichlororuthenium, Dichlorotris(triphenylphosphine)ruthenium(II), Ruthenium(II)-tris(triphenylphosphine) dichloride
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About This Item
Linear Formula:
[(C6H5)3P]3RuCl2
CAS Number:
Molecular Weight:
958.83
UNSPSC Code:
12161600
NACRES:
NA.22
PubChem Substance ID:
EC Number:
239-569-7
Beilstein/REAXYS Number:
4935939
MDL number:
Quality Level
assay
97%
reaction suitability
core: ruthenium, reagent type: catalyst
reaction type: C-H Activation
SMILES string
Cl[Ru]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9
InChI
1S/3C18H15P.2ClH.Ru/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h3*1-15H;2*1H;/q;;;;;+2/p-2
InChI key
WIWBLJMBLGWSIN-UHFFFAOYSA-L
Application
Tris(triphenylphosphine)ruthenium(II) dichloride or [RuCl2(PPh3)3] can be used as a catalyst to synthesize:
RuCl2(PPh3)3 can also be used as a catalyst in the cyclization, isomerization, reduction, oxidation, and cross-coupling reactions of a variety of organic products. Hydrogenation of nitro groups, imines, and ketones, as well as selective oxidation of alcohols are also possible in the presence of this catalyst.
- Functionalized alcohols by C-C cross-coupling reaction between different alcohols via sp3 C-H bond activation of primary alcohols in the presence of Lewis acid.
- Furan derivatives from allenyl sulfides via 1,4 migration of the sulfanyl group.
- 1,3-diphenylpropan-1-one by alkylation of acetophenone with benzyl alcohol via C-C bond formation.
- Vinyl chloride monomer by hydrochlorination reaction of acetylene.
RuCl2(PPh3)3 can also be used as a catalyst in the cyclization, isomerization, reduction, oxidation, and cross-coupling reactions of a variety of organic products. Hydrogenation of nitro groups, imines, and ketones, as well as selective oxidation of alcohols are also possible in the presence of this catalyst.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Synthesis of vinyl chloride monomer over carbon-Supported tris-(triphenylphosphine) ruthenium dichloride catalysts
Li Xing, et al.
Catalysts, 8(7), 276-276 (2018)
Cross-Coupling Reaction between Alcohols through sp3 C-H Activation Catalyzed by a Ruthenium/Lewis Acid System
Zhang S-Y, et al.
Chemistry?A European Journal , 14(33), 10201-10205 (2008)
Josanne-Dee Woodroffe et al.
ChemSusChem, 14(1), 339-343 (2020-10-21)
The sustainable, bio-based, platform chemical, 2,5-hexanedione [HD (1)], was efficiently converted to methylcyclopentadiene [MCPD (4)] through a three-step process consisting of intramolecular aldol condensation, catalytic chemoselective hydrogenation, and dehydration. Base-catalyzed aldol condensation of 1 resulted in the formation of 3-methyl-2-cyclopenten-1-one
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 223662-1G | 04061838778611 |
| 223662-5G | 04061838778628 |
| 223662-25G | 04061833545324 |