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226890

2-(Trimethylsilyl)ethanol

Name: 2-(Trimethylsilyl)ethanol
Brand: ALDRICH

96%

Synonym(s):

(2-Hydroxyethyl)trimethylsilane

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About This Item

Linear Formula:

(CH₃)₃SiCH₂CH₂OH

CAS Number:

2916-68-9

Molecular Weight:

118.25

UNSPSC Code:

12352000

NACRES:

NA.22

PubChem Substance ID:

24853596

EC Number:

220-844-5

Beilstein/REAXYS Number:

1732034

MDL number:

MFCD00002825

Assay:

96%

Form:

liquid

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Properties

Quality Level

200

assay

96%

form

liquid

refractive index

n20/D 1.423 (lit.)

bp

71-73 °C/35 mmHg (lit.)

density

0.825 g/mL at 25 °C (lit.)

functional group

hydroxyl

SMILES string

C[Si](C)(C)CCO

InChI

1S/C5H14OSi/c1-7(2,3)5-4-6/h6H,4-5H2,1-3H3

InChI key

ZNGINKJHQQQORD-UHFFFAOYSA-N

Description

Application

Protecting reagent for carboxyl and phosphate groups.

Used to synthesize Teoc-protected amines via alcoholysis of the corresponding isocyanates.

pictograms

GHS02

signalword

Warning

hcodes

H226

pcodes

P210

Hazard Classifications

Flam. Liq. 3

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

132.8 °F - closed cup

flash_point_c

56 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品

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Certificates of Analysis (COA)

Lot/Batch Number

0000380303

0000245384

0000189082

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Tetrahedron Letters, 35, 757-757 (1994)

Silicon compounds as substrates and inhibitors of acetylcholinesterase.

A Aberman et al.

Biochimica et biophysica acta, 791(2), 278-280 (1984-12-07)

Several trimethylsilyl derivatives were found to be ligands of acetylcholinesterase (acetylcholine acetylhydrolase, EC 3.1.1.7): trimethylsilylethyl acetate (III) and trimethylsilylmethyl acetate (V) are substrates of the enzyme, whereas trimethylsilylethanol (VIII) is a competitive inhibitor. The silicon compounds have kinetic parameters similar

Generation of aza-ortho-xylylenes via ring opening of 2-(2-acylaminophenyl)aziridines: application in the construction of the communesin ring system.

Seth L Crawley et al.

Organic letters, 8(18), 3995-3998 (2006-08-25)

A new protocol for generating aza-ortho-xylylenes via acid-catalyzed or fluoride-promoted ring opening of 2-(2-acylaminophenyl)aziridines is described. This methodology has been exploited in the rapid construction of a hexacyclic substructure of communesin B.

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Global Trade Item Number

SKU	GTIN
226890-1G	04061837522147
226890-50G	04061837522154
226890-10G	04061838780416