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Merck
CN

229547

Ammonium cerium(IV) nitrate

≥99.99% trace metals basis

Synonym(s):

Ceric ammonium nitrate

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About This Item

Linear Formula:
Ce(NH4)2(NO3)6
CAS Number:
Molecular Weight:
548.22
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
240-827-6
MDL number:
Assay:
≥99.99% trace metals basis
Form:
crystalline
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assay

≥99.99% trace metals basis

form

crystalline

reaction suitability

reagent type: oxidant

impurities

≤100.0 ppm Trace Metal Analysis

SMILES string

N.N.[Ce+4].O[N+]([O-])=O.O[N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/Ce.2HNO3.4NO3.2H3N/c;6*2-1(3)4;;/h;2*(H,2,3,4);;;;;2*1H3/q+4;;;4*-1;;

InChI key

WIBGOERAEYJBOT-UHFFFAOYSA-N

Application

Ammonium cerium(IV) nitrate was used to initiate the graft polymerization of polyacrylic acid with magnetic cation exchange adsorbents, which was used in conjugation with micellar aqueous two-phase systems for protein separation.
Offers a novel route to tartronic acid derivatives via facile oxygenation of malonates.


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Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Ox. Sol. 2 - Skin Corr. 1B - Skin Sens. 1A

Storage Class

5.1B - Oxidizing hazardous materials

wgk

WGK 3

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Information

危险化学品

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Articles

Oxidation and reduction reactions are some of the most common transformations encountered in organic synthesis

Rare earth elements are vital in everyday life worldwide: catalysts in cars, colors in screens, magnets in electronics. Essential for modern living.


Protein separation with magnetic adsorbents in micellar aqueous two-phase systems.
Becker JS, et al.
Separation and Purification Technology, 65.1, 46-53 (2009)
Nair, V. et al.
Tetrahedron Letters, 39, 2801-2801 (1998)
Douglas B Grotjahn et al.
Journal of the American Chemical Society, 133(47), 19024-19027 (2011-11-09)
Organometallic iridium complexes have been reported as water oxidation catalysts (WOCs) in the presence of ceric ammonium nitrate (CAN). One challenge for all WOCs regardless of the metal used is stability. Here we provide evidence for extensive modification of many



Global Trade Item Number

SKUGTIN
229547-250G04061838781925
229547-10G04061838781918
229547-50G04061838781932