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Merck
CN

229547

Ammonium cerium(IV) nitrate

≥99.99% trace metals basis

Synonym(s):

Ceric ammonium nitrate

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About This Item

Linear Formula:
Ce(NH4)2(NO3)6
CAS Number:
16774-21-3
Molecular Weight:
548.22
NACRES:
NA.23
PubChem Substance ID:
24853285
UNSPSC Code:
12352302
EC Number:
240-827-6
MDL number:
MFCD00151121
Assay:
≥99.99% trace metals basis
Form:
crystalline

Key Documents

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Product Name

Ammonium cerium(IV) nitrate, ≥99.99% trace metals basis

InChI key

WIBGOERAEYJBOT-UHFFFAOYSA-N

InChI

1S/Ce.2HNO3.4NO3.2H3N/c;6*2-1(3)4;;/h;2*(H,2,3,4);;;;;2*1H3/q+4;;;4*-1;;

SMILES string

N.N.[Ce+4].O[N+]([O-])=O.O[N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

assay

≥99.99% trace metals basis

form

crystalline

reaction suitability

reagent type: oxidant

impurities

≤100.0 ppm Trace Metal Analysis

Quality Level

200

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Application

Ammonium cerium(IV) nitrate was used to initiate the graft polymerization of polyacrylic acid with magnetic cation exchange adsorbents, which was used in conjugation with micellar aqueous two-phase systems for protein separation.
Offers a novel route to tartronic acid derivatives via facile oxygenation of malonates.

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Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Ox. Sol. 2 - Skin Corr. 1B - Skin Sens. 1A

Storage Class

5.1B - Oxidizing hazardous materials

wgk

WGK 3

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Information

危险化学品
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Certificates of Analysis (COA)

Lot/Batch Number
MKCS5028
MKCS7301
MKCS7300
MKCS4584
MKCL5272

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Protein separation with magnetic adsorbents in micellar aqueous two-phase systems.
Becker JS, et al.
Separation and Purification Technology, 65.1, 46-53 (2009)
Nair, V. et al.
Tetrahedron Letters, 39, 2801-2801 (1998)
Weibin Song et al.
Bioorganic & medicinal chemistry letters, 22(1), 387-390 (2011-11-26)
A new, practical and efficient method for the synthesis of anhydrovinblastine AVBL (1f) by oxidative coupling of vindoline and catharanthine in the presence of ceric ammonium nitrate (CAN) was developed. Under the optimized reaction conditions, we synthesized a new series
Rasika Tankhiwale et al.
Colloids and surfaces. B, Biointerfaces, 69(2), 164-168 (2009-01-10)
The present work describes ceric ammonium nitrate (CAN) initiated graft copolymerization of acrylamide onto cellulose-based filter paper followed by entrapment of silver nanoparticles. The copolymerization was carried out in aqueous solution, containing 2M acrylamide monomer and 16mM N,N'-methylene bisacrylamide (MB)
S Sudha et al.
Ultrasonics sonochemistry, 19(5), 994-998 (2012-03-09)
Tetrahydrobenzo[c]xanthenes-11-ones was synthesized by a three component reaction of α-naphthol, aromatic aldehyde and dimedone. Ceric ammonium nitrate acts as a suitable eco-friendly catalyst for this method. Shorter reaction duration, mild reaction condition and low cost make this protocol more effective.
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