245011
Triruthenium dodecacarbonyl
99%, crystals
Synonym(s):
Ruthenium carbonyl, tri-Ruthenium dodecacarbonyl
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About This Item
Linear Formula:
Ru3(CO)12
CAS Number:
Molecular Weight:
639.33
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
239-287-4
MDL number:
Product Name
Triruthenium dodecacarbonyl, 99%
Quality Segment
assay
99%
form
crystals
reaction suitability
core: ruthenium, reaction type: C-H Activation, reagent type: catalyst
SMILES string
[Ru].[Ru].[Ru].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
InChI
1S/12CO.3Ru/c12*1-2;;;
InChI key
NQZFAUXPNWSLBI-UHFFFAOYSA-N
General description
Atomic number of base material: 44 Ruthenium
Application
Carbonyl cluster precursor and H-transfer catalyst. Used in the reductive carbonylation of aromatic nitro compounds to carbamates. The phosphine-stabilized carbonyl cluster has been tethered to oxide supports. Applied in improved catalysis of the allylic amination of unactivated olefins by nitroarenes.
Catalyst used in a [3+2+1] carbonylative cycloaddition of silylacteylenes and α,β-unsaturated ketones providing good yields of α-pyrones.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Inhalation
Storage Class
11 - Combustible Solids
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
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