Skip to Content
Merck
CN

Key Documents

View All Documentation

245011

Triruthenium dodecacarbonyl

99%, crystals

Synonym(s):

Ruthenium carbonyl, tri-Ruthenium dodecacarbonyl

Sign In to View Organizational & Contract Pricing.

Select a Size

Change View

About This Item

Linear Formula:
Ru3(CO)12
CAS Number:
15243-33-1
Molecular Weight:
639.33
NACRES:
NA.22
PubChem Substance ID:
24854727
UNSPSC Code:
12161600
EC Number:
239-287-4
MDL number:
MFCD00011209
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

Product Name

Triruthenium dodecacarbonyl, 99%

Quality Segment

100

assay

99%

form

crystals

reaction suitability

core: ruthenium, reaction type: C-H Activation, reagent type: catalyst

SMILES string

[Ru].[Ru].[Ru].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

InChI

1S/12CO.3Ru/c12*1-2;;;

InChI key

NQZFAUXPNWSLBI-UHFFFAOYSA-N

General description

Atomic number of base material: 44 Ruthenium

Application

Carbonyl cluster precursor and H-transfer catalyst. Used in the reductive carbonylation of aromatic nitro compounds to carbamates. The phosphine-stabilized carbonyl cluster has been tethered to oxide supports. Applied in improved catalysis of the allylic amination of unactivated olefins by nitroarenes.
Catalyst used in a [3+2+1] carbonylative cycloaddition of silylacteylenes and α,β-unsaturated ketones providing good yields of α-pyrones.

Other Notes

A Practical Procedure for Reduction of Primary, Secondary and Tertiary Amides to Amines

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H332

Hazard Classifications

Acute Tox. 4 Inhalation

Storage Class

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library