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245011

Triruthenium dodecacarbonyl

Name: Triruthenium dodecacarbonyl
Brand: ALDRICH

99%, crystals

Synonym(s):

Ruthenium carbonyl, tri-Ruthenium dodecacarbonyl

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About This Item

Linear Formula:

Ru₃(CO)₁₂

CAS Number:

15243-33-1

Molecular Weight:

639.33

NACRES:

NA.22

PubChem Substance ID:

24854727

UNSPSC Code:

12161600

EC Number:

239-287-4

MDL number:

MFCD00011209

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Properties

Product Name

Triruthenium dodecacarbonyl, 99%

Quality Segment

100

assay

99%

form

crystals

reaction suitability

core: ruthenium, reaction type: C-H Activation, reagent type: catalyst

SMILES string

[Ru].[Ru].[Ru].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

InChI

1S/12CO.3Ru/c12*1-2;;;

InChI key

NQZFAUXPNWSLBI-UHFFFAOYSA-N

Description

General description

Atomic number of base material: 44 Ruthenium

Application

Carbonyl cluster precursor and H-transfer catalyst. Used in the reductive carbonylation of aromatic nitro compounds to carbamates. The phosphine-stabilized carbonyl cluster has been tethered to oxide supports. Applied in improved catalysis of the allylic amination of unactivated olefins by nitroarenes.

Catalyst used in a [3+2+1] carbonylative cycloaddition of silylacteylenes and α,β-unsaturated ketones providing good yields of α-pyrones.

Other Notes

A Practical Procedure for Reduction of Primary, Secondary and Tertiary Amides to Amines

Pictograms

GHS07

Signal Word

Warning

Hazard Codes

H332

Precautionary Statements

P261 - P271 - P304 + P340 + P312

Hazard Classifications

Acute Tox. 4 Inhalation

Storage Class

11 - Combustible Solids

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

PPE (personal protective equipment)

dust mask type N95 (US), Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

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