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Merck
CN

245550

4-Fluorophenylmagnesium bromide solution

2.0 M in diethyl ether

Synonym(s):

p-Fluorophenylmagnesium bromide, Bromo(4-fluorophenyl)magnesium, Bromo(p-fluorophenyl)magnesium

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About This Item

Linear Formula:
FC6H4MgBr
CAS Number:
352-13-6
Molecular Weight:
199.30
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
24854740
MDL number:
MFCD00009667
Beilstein/REAXYS Number:
636802

Key Documents

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InChI

1S/C6H4F.BrH.Mg/c7-6-4-2-1-3-5-6;;/h2-5H;1H;/q;;+1/p-1

SMILES string

Fc1ccc([Mg]Br)cc1

InChI key

QYBFFRXNNFXREA-UHFFFAOYSA-M

reaction suitability

reaction type: Grignard Reaction

concentration

2.0 M in diethyl ether

density

1.043 g/mL at 25 °C

functional group

fluoro

Quality Level

100

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Related Categories

signalword

Danger

Hazard Classifications

Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

target_organs

Central nervous system

supp_hazards

EUH014,EUH019

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

-40.0 °F - closed cup

flash_point_c

-40 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
SHBQ2494
57096DK
57097LJ
15996EJ
S37816

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S K Aggarwal et al.
Clinical chemistry, 40(8), 1494-1502 (1994-08-01)
A stable isotope dilution gas chromatography-mass spectrometry (GC-MS) method is described for the determination of lead (Pb) in urine and whole blood. The use of lithium bis(trifluoroethyl)dithiocarbamate Pb(FDEDTC) as a chelating agent showed strong memory effect, restricting the range of
R A Milius et al.
Journal of medicinal chemistry, 34(5), 1728-1731 (1991-05-01)
The synthesis and pharmacological characterization of a series of N-substituted 3-(4-fluorophenyl)tropane derivatives is reported. The compounds displayed binding characteristics that paralleled those of cocaine, and several had substantially higher affinity at cocaine recognition sites. Conjugate addition of 4-fluorophenyl magnesium bromide

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