287059
L-Prolinamide
98%, for peptide synthesis
Synonym(s):
(2S)-2-Carbamoylpyrrolidine
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About This Item
Empirical Formula (Hill Notation):
C5H10N2O
CAS Number:
Molecular Weight:
114.15
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352209
EC Number:
231-397-0
MDL number:
Beilstein/REAXYS Number:
80807
Product Name
L-Prolinamide, 98%
InChI key
VLJNHYLEOZPXFW-BYPYZUCNSA-N
InChI
1S/C5H10N2O/c6-5(8)4-2-1-3-7-4/h4,7H,1-3H2,(H2,6,8)/t4-/m0/s1
SMILES string
NC(=O)[C@@H]1CCCN1
assay
98%
optical activity
[α]20/D −106°, c = 1 in ethanol
reaction suitability
reaction type: solution phase peptide synthesis
mp
95-97 °C (lit.)
application(s)
peptide synthesis
Quality Level
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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Haizhi Zhang et al.
Analytica chimica acta, 691(1-2), 103-109 (2011-04-05)
A novel quantitative approach for the determination of sodium benzoate (SB) was proposed by the kinetic study about its competitive inhibitory efficiency to D-amino acid oxidase (DAAO) activity with a chiral ligand exchange capillary electrophoresis (CE) method, in which the
Jinsuo Gao et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 16(26), 7852-7858 (2010-05-29)
Chirally functionalized hollow nanospheres with different surface properties were successfully synthesized by co-condensation of (2S,1'R,2'R)-N-tert-butyloxycarbonylpyrrolidine-2-carboxylic acid [2'-(4-trimethoxysilylbenzylamide)cyclohexyl] amide with 1,2-bis(trimethoxysilyl)ethane or tetramethoxysilane using F127 (EO(106)PO(70)EO(106)) as surfactant in water. The TEM and N(2) sorption characterizations show that the particle size
Stamatis Fotaras et al.
Organic & biomolecular chemistry, 10(29), 5613-5619 (2012-06-22)
A tripeptide-like prolinamide-thiourea catalyst with (S)-proline, (1S,2S)-diphenylethylenediamine and (S)-di-tert-butyl aspartate as building blocks provides the products of the reaction between ketones and aromatic aldehydes in high to quantitative yields and high stereoselectivities (up to 99:1 dr and 99% ee). Both
Highly enantioselective strecker reaction of ketoimines catalyzed by an organocatalyst from (S)-BINOL and L-prolinamide.
Zongrui Hou et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 14(15), 4484-4486 (2008-04-11)
Kazuhiko Mitsui et al.
Chemical communications (Cambridge, England), (22)(22), 3261-3263 (2009-07-10)
Dendritic effects on both the enantioselectivity and diastereoselectivity of the direct aldol reaction were observed for pyridine-2,6-dicarboxamide dendrons terminated with L-prolinamides.
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