291005
Butylmagnesium chloride solution
2.0 M in THF
Synonym(s):
BuMgCl
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About This Item
Linear Formula:
CH3(CH2)3MgCl
CAS Number:
Molecular Weight:
116.87
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3587228
Concentration:
2.0 M in THF
Quality Level
reaction suitability
reaction type: Grignard Reaction
packaging
Sure/Seal™ of
concentration
2.0 M in THF
density
0.962 g/mL at 25 °C
SMILES string
CCCC[Mg]Cl
InChI
1S/C4H9.ClH.Mg/c1-3-4-2;;/h1,3-4H2,2H3;1H;/q;;+1/p-1
InChI key
UUNGXYVLXYGZKH-UHFFFAOYSA-M
Application
Butylmagnesium chloride (BuMgCl) is a Grignard reagent that can be used:
- To prevent the formation of passivating surface films on Mg electrodes.
- For the synthesis of lithium tributylmagnesate complex (n-Bu3MgLi) by reacting with n-BuLi.
Legal Information
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
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signalword
Danger
target_organs
Central nervous system, Respiratory system
supp_hazards
Storage Class
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
1.4 °F - closed cup
flash_point_c
-17 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react. 1
Regulatory Information
危险化学品
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Tributylmagnesium ate complex-mediated novel bromine-magnesium exchange reaction for selective monosubstitution of dibromoarenes.
Iida T, et al.
Tetrahedron Letters, 42(29), 4841-4844 (2001)
On the electrochemical behavior of magnesium electrodes in polar aprotic electrolyte solutions.
Lu Z, et al.
Journal of Electroanalytical Chemistry, 466(2), 203-217 (1999)
B Pons et al.
Journal of chromatography. B, Biomedical sciences and applications, 716(1-2), 139-145 (1998-11-21)
One analytical procedure for the determination of ionic alkyllead in human urine has been studied. The system consists of the extraction of Me3Pb+, Et3Pb+ and Pb2+ at pH 9.0 with diethyldithiocarbamate to an organic phase. Then, the ionic compounds are
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 291005-100ML | 04061826541210 |
| 291005-800ML | 04061826541227 |