Skip to Content
Merck
CN

298980

o-Tolylmagnesium bromide solution

2.0 M in diethyl ether

Synonym(s):

2-Methylphenylmagnesium bromide, 2-Tolylmagnesium bromide, o-Methylphenylmagnesium bromide, Bromo(2-methylphenyl)magnesium, Bromo-o-tolylmagnesium

Sign In to View Organizational & Contract Pricing.

Select a Size

About This Item

Linear Formula:
CH3C6H4MgBr
CAS Number:
932-31-0
Molecular Weight:
195.34
NACRES:
NA.22
PubChem Substance ID:
24858005
UNSPSC Code:
12352103
MDL number:
MFCD00010350

Key Documents

View All Documentation
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

Product Name

o-Tolylmagnesium bromide solution, 2.0 M in diethyl ether

InChI

1S/C7H7.BrH.Mg/c1-7-5-3-2-4-6-7;;/h2-5H,1H3;1H;/q;;+1/p-1

SMILES string

Cc1ccccc1[Mg]Br

InChI key

DVXDIGKNJYSMFM-UHFFFAOYSA-M

reaction suitability

reaction type: Grignard Reaction

concentration

2.0 M in diethyl ether

density

1.013 g/mL at 25 °C

Quality Level

100

Related Categories

Application

o-Tolylmagnesium bromide solution can be used to prepare:
  • An iridium(I) mesityl complex named Ir(o-tolyl)(CO)(dppe).
  • 4-(2-Methylphenyl)-4-oxobutanoic acid, a key intermediate for the synthesis of M1 muscarinic selective agonist AC-42 derivatives.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

target_organs

Central nervous system

supp_hazards

EUH014,EUH019

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

-40.0 °F

flash_point_c

-40 °C

Regulatory Information

新产品
This item has

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
S38335
S35940
07413JD
S29456
S27025

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Synthesis and Reactivity of the Iridium (I) Mesityl Complex Ir (CO)(mes)(dppe). Oxidative Addition and Ligand Activation Reactions
Cleary BP and Eisenberg R
Journal of the American Chemical Society, 117(12), 3510-3521 (1995)
Fluorescent derivatives of AC-42 to probe bitopic orthosteric/allosteric binding mechanisms on muscarinic M1 receptors
Daval SB, et al.
Journal of Medicinal Chemistry, 55(5), 2125-2143 (2012)
Chihiro Tsukano et al.
Chemical & pharmaceutical bulletin, 65(12), 1167-1174 (2017-12-05)
Tetrahydrobiphenylene consists of cyclobutene fused with benzene and cyclohexene rings. In this paper, a direct method for synthesizing tetrahydrobiphenylenes based on a palladium (Pd)(0)-catalyzed C(sp

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service