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Merck
CN

302767

(S)-(−)-1-Methyl-2-pyrrolidinemethanol

96%

Synonym(s):

N-Methyl-L-prolinol, (S)-2-Hydroxymethyl-1-methylpyrrolidine

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About This Item

Empirical Formula (Hill Notation):
C6H13NO
CAS Number:
34381-71-0
Molecular Weight:
115.17
UNSPSC Code:
12352209
NACRES:
NA.22
PubChem Substance ID:
24858272
EC Number:
251-981-9
Beilstein/REAXYS Number:
79851
MDL number:
MFCD00011727

Key Documents

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Product Name

(S)-(−)-1-Methyl-2-pyrrolidinemethanol, 96%

form

liquid

assay

96%

InChI key

VCOJPHPOVDIRJK-LURJTMIESA-N

InChI

1S/C6H13NO/c1-7-4-2-3-6(7)5-8/h6,8H,2-5H2,1H3/t6-/m0/s1

SMILES string

CN1CCC[C@H]1CO

optical activity

[α]19/D −49.5°, c = 5 in methanol

reaction suitability

reaction type: solution phase peptide synthesis

refractive index

n20/D 1.469 (lit.)

bp

67-69 °C/12 mmHg (lit.)

density

0.968 g/mL at 25 °C (lit.)

application(s)

peptide synthesis

storage temp.

2-8°C

Quality Level

100

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Related Categories

Application

Precursor to phosphine ligands for catalytic asymmetric Grignard cross-coupling reactions.

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

145.4 °F - closed cup

flash_point_c

63 °C - closed cup

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

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Certificates of Analysis (COA)

Lot/Batch Number
MKCS2771
MKCM1400
MKCH1665
MKBL7399V
MKAA1506V

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Dan Loewenthal et al.
Archives of toxicology, 94(11), 3751-3757 (2020-07-29)
We present a simple method for chiral separation and analysis of organophosphorus nerve agents and apply it to monitor the enantioselective blood elimination kinetics of sarin in-vitro. The method is implemented in standard reverse phase LC-MS operating conditions, relieving the
The Journal of Organic Chemistry, 48, 2195-2195 (1983)

Articles

Chiral Vicinal Diamines for Asymmetric Synthesis

Chiral vicinal diamines are of tremendous interest to the synthetic chemist as they are found in many chiral catalysts and pharmaceuticals.

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