338257
异丁基溴化镁 溶液
2.0 M in diethyl ether
别名:
iBuMgBr solution
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关于此项目
线性分子式:
(CH3)2CHCH2MgBr
化学文摘社编号:
分子量:
161.32
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
Concentration:
2.0 M in diethyl ether
Form:
liquid
form
liquid
Quality Segment
reaction suitability
reaction type: Grignard Reaction
packaging
Sure/Seal™ of
concentration
2.0 M in diethyl ether
density
0.941 g/mL at 25 °C
SMILES string
CC(C)C[Mg]Br
InChI
1S/C4H9.BrH.Mg/c1-4(2)3;;/h4H,1H2,2-3H3;1H;/q;;+1/p-1
InChI key
CMWBEISSZHZIMU-UHFFFAOYSA-M
Application
Isobutylmagnesium bromide (iBuMgBr) is a general Grignard reagent used in the total synthesis of (+)-rishirilide B, glucolipsin A, and (+)-juvabione. It can also be used as a reagent in the synthesis of pyrrolidine-based influenza neuraminidase (NA) inhibitors.
Legal Information
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 1 - Skin Irrit. 2 - STOT SE 3
target_organs
Central nervous system
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
-29.2 °F - closed cup
flash_point_c
-34 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves