346152
Ethynylmagnesium bromide solution
0.5 M in THF
Synonym(s):
Acetylenemagnesium bromide, Bromoethynylmagnesium, Ethynylmagnesium bromide
Sign In to View Organizational & Contract Pricing.
Select a Size
Change View
About This Item
Linear Formula:
HC≡CMgBr
CAS Number:
Molecular Weight:
129.24
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3600874
Quality Level
reaction suitability
reaction type: Grignard Reaction
packaging
Sure/Seal™ of
concentration
0.5 M in THF
density
0.94 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
Br[Mg]C#C
InChI
1S/C2H.BrH.Mg/c1-2;;/h1H;1H;/q;;+1/p-1
InChI key
HUGJUYPSXULVQQ-UHFFFAOYSA-M
General description
Ethynylmagnesium bromide solution, also known as bromoethynylmagnesium, is a grignard reagent that is commonly used in the synthesis of polymers, and unsaturated phosphonites.
Application
Ethynylmagnesium bromide solution can be used in:
- Grafting of aliphatic polymer.
- Synthesis of anthracene-containing species like 1,8-dichloro-10-(ethynyl)anthracene.
- The preparation of the alkyne component in an enyne cross-metathesis leading to conjugated dienes.
- Ethynylation of chiral α-(dibenzylamino) aldehydes.
- The synthesis of ethynyl aziridines.
- To prepare alkyl(triethynyl)germanes from tert-alkyltrichlorogermanes and 2-butyltrichlorogermane.
- The preperation of a key intermediate in the total synthesis of (+)-4-demethoxydaunomycin.
Legal Information
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
signalword
Danger
target_organs
Respiratory system
supp_hazards
Storage Class
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
-20.2 °F
flash_point_c
-29 °C
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react. 2
Regulatory Information
危险化学品
This item has
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
Grafting of functionalized polymer on porous silicon surface using Grignard reagent
FZ T,et al.
Applied Surface Science, 421, 82-88 (2017)
Improved Access to 1, 8-Dichloro-10-(ethynyl) anthracene: A Useful Building Block for (Semi-) rigid Organic Frameworks
Jan-Hendrik L,et al.
Synthesis, 50, 2009-2018 (2018)
An enantioselective formal synthesis of 4-demethoxydaunomycin using the catalytic asymmetric ring opening reaction of meso-epoxide with p-anisidine
Sekine A, et al.
Tetrahedron, 58(1), 75-82 (2002)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 346152-PZ | 04061823834124 |
| 346152-100ML | 04061826760987 |
| 346152-800ML | 04061826760994 |