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419613

2-Methyl-1-propenylmagnesium bromide solution

0.5 M in THF

Synonym(s):

(2-Methylpropenyl)magnesium bromide, 2,2-Dimethylvinylmagnesium bromide, Isobutenylmagnesium bromide

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About This Item

Linear Formula:
(CH3)2C=CHMgBr
CAS Number:
38614-36-7
Molecular Weight:
159.31
NACRES:
NA.22
PubChem Substance ID:
24866265
UNSPSC Code:
12352103
MDL number:
MFCD00209600
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Quality Segment

100

reaction suitability

reaction type: Grignard Reaction

packaging

Sure/Seal™ of

concentration

0.5 M in THF

density

0.952 g/mL at 25 °C

SMILES string

C\C(C)=C\[Mg]Br

InChI

1S/C4H7.BrH.Mg/c1-4(2)3;;/h1H,2-3H3;1H;/q;;+1/p-1

InChI key

BKVIQODYSREJQH-UHFFFAOYSA-M

General description

2-Methyl-1-propenylmagnesiumbromide is a heterocyclic organic compound. It is used as a Grignard reagent in chemical synthesis.

Application

Used in a study of a palladium-catalyzed coupling with aryl tosylates.
Used in a synthesis of (2S,3S)-3′-fluoroisoleucine.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

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Danger

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

flash_point_f

5.0 °F - closed cup

flash_point_c

-15 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

target_organs

Central nervous system, Respiratory system

supp_hazards

EUH019

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react. 2

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