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547751

Tris[N,N-bis(trimethylsilyl)amide]scandium(III)

Name: Tris[<I>N</I>,<I>N</I>-bis(trimethylsilyl)amide]scandium(III)
Brand: ALDRICH

97%

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About This Item

Linear Formula:

Sc(N(Si(CH₃)₃)₂)₃

CAS Number:

37512-28-0

Molecular Weight:

526.11

UNSPSC Code:

12352300

PubChem Substance ID:

24878977

MDL number:

MFCD03427088

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Properties

assay

97%

mp

169-174 °C (lit.)

SMILES string

C[Si](C)(C)N([Sc](N([Si](C)(C)C)[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C

Description

pictograms

GHS02,GHS05

signalword

Danger

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 3

flash_point_f

35.6 °F - closed cup

flash_point_c

2.0 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Hazard Classifications

Flam. Sol. 1 - Skin Corr. 1B - Water-react. 2

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number

02222EE

15314CO

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Gas chromatography-mass spectrometry of the trimethylsilyl (oxime) ether/ester derivatives of cholic acids: their presence in the aquatic environment.

A Sebok et al.

Journal of chromatography. A, 1211(1-2), 104-112 (2008-10-14)

This paper presents a derivatization, mass fragmentation study relating to the most common six cholic acids, such as cholic, lithocholic, chenodeoxycholic, ursodeoxycholic, 3-hydroxy,7-ketocholanic and dehydrocholic acids, identified and quantified as pollutants in the aquatic environment at the first time. Derivatizations

An Ugi reaction in the total synthesis of (-)-dysibetaine.

Jerry Isaacson et al.

Angewandte Chemie (International ed. in English), 48(10), 1845-1848 (2009-01-29)

(-)-Dysibetaine has been synthesized in 11 steps from readily available L-malic acid (see scheme). The key step is a unique Ugi 4-center-3-component cyclization reaction, where an ester group acts as the carboxylic acid component. The use of 1,1,1,3,3,3-hexamethyldisilazane as an

Reactions of (-)-sparteine with alkali metal HMDS complexes: conventional meets the unconventional.

Natalie M Clark et al.

Chemical communications (Cambridge, England), (39)(39), 5835-5837 (2009-09-30)

'Conventional' (-)-sparteine adducts of lithium and sodium 1,1,1,3,3,3-hexamethyldisilazide (HMDS) were prepared and characterised, along with an unexpected and 'unconventional' hydroxyl-incorporated sodium sodiate, [(-)-sparteine x Na(mu-HMDS)Na x (-)-sparteine](+)[Na(4)(mu-HMDS)(4)(OH)](-)--the complex anion of which is the first inverse crown ether anion.

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Global Trade Item Number

SKU	GTIN
700159P-5MG	04061835384006