683221
[Ru(benzene)Cl2]2
Umicore
Synonym(s):
Benzeneruthenium(II) chloride dimer, Dichloro(benzene)ruthenium(II)-dimer, Bis[(benzene)dichlororuthenium], Dibenzenetetrachlorodiruthenium
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About This Item
InChI
1S/2C6H6.4ClH.2Ru/c2*1-2-4-6-5-3-1;;;;;;/h2*1-6H;4*1H;;/q;;;;;;2*+2/p-4
SMILES string
Cl[Ru]Cl.Cl[Ru]Cl.c1ccccc1.c2ccccc2
InChI key
YGXMUPKIEHNBNQ-UHFFFAOYSA-J
form
powder
reaction suitability
core: ruthenium, reagent type: catalyst
Application
- Catalyst for SNAr reactions of fluoroarenes and cyclic amines (eq. 1)
- Precatalyst for the hydrogenation of β-keto esters (eq. 2)
- Precursor for the preparation of other ruthenium catalysts (eq. 3)
Legal Information
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Precatalysts for asymmetric catalysis offer batch-to-batch consistency in a range of catalytic reactions, supporting diverse research needs.
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