685062
(1,5-Cyclooctadiene)(methoxy)iridium(I) dimer
crystals
Synonym(s):
[Ir(OMe)(1,5-cod)]2, Bis(1,5-cyclooctadiene)di-μ-methoxydiiridium(I)
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About This Item
Product Name
(1,5-Cyclooctadiene)(methoxy)iridium(I) dimer,
form
crystals
Quality Level
reaction suitability
core: iridium, reagent type: catalyst
reaction type: C-H Activation
mp
154-179 °C (D)
storage temp.
−20°C
SMILES string
C[O+]1[Ir-]2[O+](C)[Ir-]12.C3CC=CCCC=C3.C4CC=CCCC=C4
InChI
1S/2C8H12.2CH3O.2Ir/c2*1-2-4-6-8-7-5-3-1;2*1-2;;/h2*1-2,7-8H,3-6H2;2*1H3;;/q;;2*+1;2*-1/b2*2-1-,8-7-;;;;
InChI key
BGWIAAATAAWGOI-MIXQCLKLSA-N
Application
- Preparation of heteroaryl fused indole ring systems as inhibitors of HCV NS5B polymerase
- Borylation/Suzuki-Miyaura coupling
- Metalation-Suzuki cross-coupling procedure for the synthesis of biaryls and heterobiaryls
- Tetraborylation reactions
- Highly regio- and enantioselective asymmetric hydroboration
- Ortho-silylation of aryl ketone, benzaldehyde, and benzyl alcohol derivatives via C-H activation
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Articles
Arylboronic acids and esters, vital tools in chemical transformations, find extensive use, particularly in the Suzuki-Miyaura cross-coupling reaction.
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 685062-250MG | 04061833564929 |
| 685062-25G | 04061833490624 |
| 685062-1G | 04061832758848 |