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Merck
CN

703575

Phenylmagnesium bromide solution

greener alternative

2.9 M in 2-methyltetrahydrofuran

Synonym(s):

Bromomagnesiobenzene, Bromophenylmagnesium

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About This Item

Linear Formula:
C6H5MgBr
CAS Number:
100-58-3
Molecular Weight:
181.31
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
329762051
MDL number:
MFCD00000038
Beilstein/REAXYS Number:
3588849

Key Documents

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Product Name

Phenylmagnesium bromide solution, 2.9 M in 2-methyltetrahydrofuran

InChI

1S/C6H5.BrH.Mg/c1-2-4-6-5-3-1;;/h1-5H;1H;/q;;+1/p-1

SMILES string

Br[Mg]c1ccccc1

InChI key

ANRQGKOBLBYXFM-UHFFFAOYSA-M

form

liquid

reaction suitability

reaction type: Grignard Reaction

greener alternative product characteristics

Safer Solvents and Auxiliaries
Use of Renewable Feedstocks
Inherently Safer Chemistry for Accident Prevention
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

concentration

2.9 M in 2-methyltetrahydrofuran
45 % (w/w)

density

1.161 g/mL at 25 °C

greener alternative category

Aligned,

Quality Level

100

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Application

Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product, 2.9 M in 2-methyltetrahydrofuran aligns with "Safer Solvents and Auxiliaries", "Use of Renewable Feedstocks" and "Inherently Safer Chemistry for Accident Prevention". Click here for more information.

Legal Information

Product of Albemarle US Inc

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Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

supp_hazards

EUH014,EUH019

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

12.2 °F

flash_point_c

-11 °C

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
SHBP7907
SHBM8063
SHBK9087
SHBK3904
SHBJ2216

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Ying Li et al.
Analytica chimica acta, 884, 106-113 (2015-06-16)
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