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Sigma-Aldrich

2-Cyano-2-propyl benzodithioate

>97% (HPLC)

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Synonym(s):
2-Cyanopropan-2-yl benzodithioate
Empirical Formula (Hill Notation):
C11H11NS2
CAS Number:
Molecular Weight:
221.34
MDL number:
PubChem Substance ID:
NACRES:
NA.23

Quality Level

Assay

>97% (HPLC)

form

solid or liquid

refractive index

n20/D 1.621

mp

28-31 °C

density

1.146 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

CC(C)(SC(=S)c1ccccc1)C#N

InChI

1S/C11H11NS2/c1-11(2,8-12)14-10(13)9-6-4-3-5-7-9/h3-7H,1-2H3

InChI key

IDSLBLWCPSAZBL-UHFFFAOYSA-N

Related Categories

General description

Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.

Application

RAFT agent for controlled radical polymerization; especially suited for the polymerization of methacrylate and methacrylamide monomers. Chain Transfer Agent (CTA)

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Skin Sens. 1

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

230.0 °F - closed cup

Flash Point(C)

> 110 °C - closed cup


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Xiaohan Zhang et al.
Langmuir : the ACS journal of surfaces and colloids, 34(27), 7998-8006 (2018-06-28)
Amphiphilic poly( N-(2-hydroxypropyl)methacrylamide) copolymers ( pHPMA) bearing cholesterol side groups in phosphate buffer saline self-assemble into nanoparticles (NPs) which can be used as tumor-targeted drug carriers. It was previously shown by us that human serum albumin (HSA) interacts weakly with
Ryuichi Nakatani et al.
ACS applied materials & interfaces, 9(37), 31266-31278 (2017-03-18)
In this study, a series of perpendicular lamellae-forming poly(polyhedral oligomeric silsesquioxane methacrylate-block-2,2,2-trifluoroethyl methacrylate)s (PMAPOSS-b-PTFEMAs) was developed based on the bottom-up concept of creating a simple yet effective material by tailoring the chemical properties and molecular composition of the material. The
Yixiao Dong et al.
Acta biomaterialia, 108, 56-66 (2020-04-07)
Injury to the skin from severe burns can cause debilitating physical and psychosocial distress to the patients. Upon healing, deep dermal burns often result in devastating hypertrophic scar formation. For many decades, stem cell-based therapies have shown significant potential in
Laura Marcela Forero Ramirez et al.
Carbohydrate polymers, 224, 115153-115153 (2019-09-02)
A multi-reactive polysaccharide-based transurf (acting both as macro-Chain Transfer Agent and stabilizer) was used to confine RAFT polymerization of methyl methacrylate (MMA) at the oil/water (o/w) miniemulsion interface. Dithiobenzoate groups and hydrophobic aliphatic side chains were introduced onto dextran, conferring
Laure Gevaux et al.
Polymers, 11(2) (2019-04-10)
Fouling Release Coatings are marine antifouling coatings based on silicone elastomers. Contrary to commonly used biocide-based antifouling coatings, they do not release biocides into the marine environment, however, they suffer from poor antifouling efficacy during idle periods. To improve their

Articles

RAFT polymerization uses commercial agents to control polymer properties without cytotoxic heavy metals like ATRP.

RAFT (Reversible Addition Fragmentation chain Transfer) polymerization is a reversible deactivation radical polymerization (RDRP) and one of the more versatile methods for providing living characteristics to radical polymerization.

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RAFT polymerization offers precise control, enabling tailored synthesis of complex polymer structures.

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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