Skip to Content
Merck
CN

Key Documents

View All Documentation

745480

Zinc isopropylsulfinate

95%

Synonym(s):

Baran Isopropylation Reagent, Baran IPS Reagent, Bis((isopropylsulfinyl)oxy)zinc, IPS

Sign In to View Organizational & Contract Pricing.

Select a Size

Change View

About This Item

Empirical Formula (Hill Notation):
C6H14O4S2Zn
CAS Number:
1416821-55-0
Molecular Weight:
279.69
NACRES:
NA.22
PubChem Substance ID:
329764984
UNSPSC Code:
12352001
MDL number:
MFCD24386390
Assay:
95%
Form:
solid
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

Quality Segment

100

assay

95%

form

solid

reaction suitability

reaction type: Allylation, reaction type: C-C Bond Formation, reagent type: catalyst
reaction type: C-H Activation, reagent type: diversification reagent

mp

161-166 °C

functional group

sulfinic acid

SMILES string

CC(C)S(=O)O[Zn]OS(=O)C(C)C

InChI

1S/2C3H8O2S.Zn/c2*1-3(2)6(4)5;/h2*3H,1-2H3,(H,4,5);/q;;+2/p-2

InChI key

PEEMMWYYSHSBTQ-UHFFFAOYSA-L

Application

Zinc isopropylsulfinate (IPS) is part of a zinc sulfinate toolbox developed by Phil Baran for the simple and rapid diversification of heterocycles.


Practical and Innate Carbon-Hydrogen Functionalization of Heterocycles

Learn More at the Professor and Product Portal of Professor Phil S. Baran.

Preparation Note

may contain up to 1 mole eq ZnCl2

Other Notes

Frequently Asked Questions are available for this Product.
Previously sold under product number L511161

signalword

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
MKCN1076
MKCJ2637
MKCD0333
MKCB0914V
MKBX5822V

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Articles

Baran Diversinates™

Rapidly diversify (hetero)aromatic scaffolds for chemical industry needs amid resource and time constraints, ensuring efficiency.

Chun You et al.
Biotechnology and bioengineering, 114(8), 1855-1864 (2017-04-15)
Myo-Inositol (vitamin B8) is widely used in the drug, cosmetic, and food & feed industries. Here, we present an in vitro non-fermentative enzymatic pathway that converts starch to inositol in one vessel. This in vitro pathway is comprised of four
Rie Poulsen et al.
Trials, 18(1), 578-578 (2017-12-05)
Depression and anxiety are among the largest contributors to the global burden of disease and have negative effects on both the individual and society. Depression and anxiety are very likely to influence the individual's work ability, and up to 40%
Q van Geest et al.
NeuroImage. Clinical, 19, 507-515 (2018-07-10)
To explore the added value of dynamic functional connectivity (dFC) of the default mode network (DMN) during resting-state (RS), during an information processing speed (IPS) task, and the within-subject difference between these conditions, on top of conventional brain measures in
View All Related Papers

Global Trade Item Number

SKUGTIN
745480-1G04061826645321
745480-10G04061833433041
745480-100MG04061833233788