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806501

Boc-Thr(t-Bu)-OH

95%, powder

Synonym(s):

(S)-3-tert-Butoxy-2-tert-butoxycarbonylamino-butyric acid, Boc-O-tert-butyl-L-threonine

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About This Item

Linear Formula:
(CH3)3COCH(CH3)CH(COOH)NHCOOC(CH3)3
CAS Number:
13734-40-2
Molecular Weight:
275.34
NACRES:
NA.22
PubChem Substance ID:
329769015
UNSPSC Code:
12352209
MDL number:
MFCD00151115
Beilstein/REAXYS Number:
4454820
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Product Name

Boc-Thr(t-Bu)-OH,

assay

95%

Quality Level

100

form

powder

mp

98.9 °C

application(s)

peptide synthesis

storage temp.

2-8°C

SMILES string

C[C@@H](OC(C)(C)C)[C@H](NC(=O)OC(C)(C)C)C(O)=O

InChI

1S/C13H25NO5/c1-8(18-12(2,3)4)9(10(15)16)14-11(17)19-13(5,6)7/h8-9H,1-7H3,(H,14,17)(H,15,16)/t8-,9+/m1/s1

InChI key

LKRXXARJBFBMCE-BDAKNGLRSA-N

General description

Boc-Thr(t-Bu)-OH (N-Boc-O-tert-butyl-L-threonine) participates in the synthesis of 2,3-unsaturated glycosides, via reaction with per-O-acetylated glucal in the presence of Er(OTf)3 catalyst.

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Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKBW7782

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Carbohydrate research, 342(14), 2125-2131 (2007-06-23)
Er(OTf)(3) is a useful catalyst for the Ferrier rearrangement furnishing high yields of O- and S-glycosides. The transformation has wide applicability, cleaner reaction profiles, mild reaction conditions, and high stereoselectivity and the catalyst, which is also commercially available, can be
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Global Trade Item Number

SKUGTIN
806501-250MG04061833232583