900942
Chloro(4-cyanophenyl)[(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldiphenylphosphine]nickel(II)
≥95%, powder or solid
Synonym(s):
SK-J004-1n
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About This Item
Empirical Formula (Hill Notation):
C43H48ClFeNNiP2
CAS Number:
Molecular Weight:
790.79
MDL number:
UNSPSC Code:
12352103
NACRES:
NA.22
Product Name
Chloro(4-cyanophenyl)[(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldiphenylphosphine]nickel(II), ≥95%
SMILES string
C[Ni+]C1=CC=C(C#N)C=C1.[C]2(CP(C3=CC=CC=C3)C4=CC=CC=C4)[C][C][C][C]2P(C5CCCCC5)C6CCCCC6.[C]7[C][C][C][C]7.[Fe]
assay
≥95%
form
powder or solid
reaction suitability
core: nickel
reaction type: Cross Couplings
reagent type: catalyst
Quality Level
Application
Amination of aryl chlorides with ammonium salts.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Nickel?Catalyzed Amination of Aryl Chlorides with Ammonia or Ammonium Salts.
Green R A and Hartwig J F
Angewandte Chemie (International Edition in English), 54(12), 3768-3772 (2015)
Ni?Catalyzed Amination Reactions: An Overview.
Marin M, et al.
Chemical Record, 16(4), 1819-1832 (2016)
Evaluating 1, 1?-Bis (phosphino) ferrocene Ancillary Ligand Variants in the Nickel-Catalyzed C?N Cross-Coupling of (Hetero) aryl Chlorides.
Clark J S, et al.
Organometallics, 36(3), 679-686 (2017)
Nickel?Catalyzed Monoarylation of Ammonia.
Borzenko A, et al.
Angewandte Chemie (International Edition in English), 54(12), 3773-3777 (2015)
Sarah Z Tasker et al.
Nature, 509(7500), 299-309 (2014-05-16)
Tremendous advances have been made in nickel catalysis over the past decade. Several key properties of nickel, such as facile oxidative addition and ready access to multiple oxidation states, have allowed the development of a broad range of innovative reactions.
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