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901126

trans-Bis(tribenzylphosphine)(2-methylphenyl)nickel(II) chloride

95%

Synonym(s):

trans-(PBn3)2Ni(o-tolyl)Cl

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About This Item

Empirical Formula (Hill Notation):
C49H49ClNiP2
CAS Number:
1594112-87-4
Molecular Weight:
794.01
UNSPSC Code:
12352200
Assay:
95%
Form:
powder or solid
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assay

95%

form

powder or solid

reaction suitability

reaction type: Cross Couplings, reagent type: catalyst

mp

200-205 °C

SMILES string

Cl[Ni](C1=C(C)C=CC=C1)(P(CC2=CC=CC=C2)(CC3=CC=CC=C3)CC4=CC=CC=C4)P(CC5=CC=CC=C5)(CC6=CC=CC=C6)CC7=CC=CC=C7

Application

The following Ni-complex is an air-stable precatalyst for various Ni-catalyzed reactions which normally require Ni(cod)2, however, this precatalyst will not require any glovebox or schlenk techniques that must be followed with Ni(cod)2. Rates are enhanced and selectivity is maintained when compared to the same reaction with Ni(cod)2.

Other Notes

Legal Information

Patent application PCT/US2014/064565. Sold under license from the Massachusetts Institute of Technology.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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