912727
(2R,3R)-iPr-BIDIME
Synonym(s):
(2R,3R)-3-(Tert-butyl)-4-(2,6-dimethoxyphenyl)-2-isopropyl-2,3-dihydrobenzo[d][1,3]oxaphosphole
Sign In to View Organizational & Contract Pricing.
Select a Size
About This Item
Empirical Formula (Hill Notation):
C22H29O3P
CAS Number:
Molecular Weight:
372.44
MDL number:
UNSPSC Code:
12352200
NACRES:
NA.22
InChI key
AVUPKIFOTAYCAC-OSMGYRLQSA-N
InChI
1S/C22H29O3P/c1-14(2)21-25-18-13-8-10-15(20(18)26(21)22(3,4)5)19-16(23-6)11-9-12-17(19)24-7/h8-14,21H,1-7H3/t21-,26?/m1/s1
SMILES string
P1([C@@H](Oc2c1c(ccc2)c3c(cccc3OC)OC)C(C)C)C(C)(C)C
form
powder and chunks
optical purity
ee: ≥99% (HPLC)
reaction suitability
reagent type: ligand
functional group
phosphine
Quality Level
Related Categories
Application
(2R,3R)-iPr-BIDIME is a P-chiral monophosphorus ligand used for the transition metal-catalyzed asymmetric Suzuki-Miyaura and hydroboration reactions.
Legal Information
Sold in collaboration with Zejun Pharmaceuticals
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
新产品
This item has
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
Guangqing Xu et al.
Journal of the American Chemical Society, 136(2), 570-573 (2013-10-24)
Efficient asymmetric Suzuki-Miyaura coupling reactions are employed for the first time in total syntheses of chiral biaryl natural products korupensamine A and B in combination with an effective diastereoselective hydrogenation, allowing ultimately a concise and stereoselective synthesis of michellamine B.
Naifu Hu et al.
Journal of the American Chemical Society, 137(21), 6746-6749 (2015-05-06)
The rhodium-catalyzed asymmetric hydroboration of α-arylenamides with BI-DIME as the chiral ligand and (Bpin)2 as the reagent yields for the first time a series of α-amino tertiary boronic esters in good yields and excellent enantioselectivities (up to 99% ee).
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
Contact Technical Service