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912727

(2R,3R)-iPr-BIDIME

Name: (2<I>R</I>,3<I>R</I>)-iPr-BIDIME
Brand: ALDRICH

Synonym(s):

(2R,3R)-3-(Tert-butyl)-4-(2,6-dimethoxyphenyl)-2-isopropyl-2,3-dihydrobenzo[d][1,3]oxaphosphole

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About This Item

Empirical Formula (Hill Notation):

C₂₂H₂₉O₃P

CAS Number:

1477517-19-3

Molecular Weight:

372.44

MDL number:

MFCD31630762

UNSPSC Code:

12352200

NACRES:

NA.22

Form:

powder and chunks

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Properties

form

powder and chunks

Quality Segment

100

optical purity

ee: ≥99% (HPLC)

reaction suitability

reagent type: ligand

functional group

phosphine

SMILES string

P1([C@@H](Oc2c1c(ccc2)c3c(cccc3OC)OC)C(C)C)C(C)(C)C

InChI

1S/C22H29O3P/c1-14(2)21-25-18-13-8-10-15(20(18)26(21)22(3,4)5)19-16(23-6)11-9-12-17(19)24-7/h8-14,21H,1-7H3/t21-,26?/m1/s1

InChI key

AVUPKIFOTAYCAC-OSMGYRLQSA-N

Description

Application

(2R,3R)-iPr-BIDIME is a P-chiral monophosphorus ligand used for the transition metal-catalyzed asymmetric Suzuki-Miyaura and hydroboration reactions.

Other Notes

Synthesis of Chiral α-Amino Tertiary Boronic Esters by Enantioselective Hydroboration of α-Arylenamides

Legal Information

Sold in collaboration with Zejun Pharmaceuticals

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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