918083
2,9-Dimethyl-1,10-phenanthroline nickel (ll) bromide
powder
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About This Item
Empirical Formula (Hill Notation):
C14H12Br2N2Ni
CAS Number:
Molecular Weight:
426.76
UNSPSC Code:
12352200
Form:
powder
Product Name
2,9-Dimethyl-1,10-phenanthroline nickel (ll) bromide,
form
powder
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
mp
>300 °C
Application
2,9-Dimethyl-1,10-phenanthroline nickel (ll) bromide is a Ni precatalyst used for a variety of cross-coupling reactions.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Qing-Yuan Meng et al.
Angewandte Chemie (International ed. in English), 56(43), 13426-13430 (2017-08-24)
We report the efficient carboxylation of bromides and triflates with K2 CO3 as the source of CO2 in the presence of an organic photocatalyst in combination with a nickel complex under visible light irradiation at room temperature. The reaction is
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