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Merck
CN

928305

cataCXium® A Pd G3 ChemBeads

solid

Synonym(s):

Mesylate[(di(1-adamantyl)-n-butylphosphine)-2-(2′-amino-1,1′-biphenyl)]palladium(II), [(Di(1-adamantyl)-butylphosphine)-2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate, cataCXium-A-Pd-G3

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About This Item

Empirical Formula (Hill Notation):
C37H52NO3PPdS
CAS Number:
1651823-59-4
Molecular Weight:
728.27
MDL number:
MFCD28144563
UNSPSC Code:
12352101
NACRES:
NA.82

Key Documents

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Product Name

cataCXium® A Pd G3 ChemBeads,

InChI key

QFHMWCPYABRFMY-UHFFFAOYSA-M

SMILES string

[Pd+2].P(C76CC8CC(C7)CC(C6)C8)(C43CC5CC(C4)CC(C3)C5)CCCC.[S](=O)(=O)([O-])C.Nc1c(cccc1)c2[c-]cccc2

Quality Level

100

product line

ChemBeads

form

solid

composition

~ 4 wt.% loading of catalyst

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

Related Categories

Application

cataCXium® A Pd G3 is a Buchwald third generation precatalyst that can be used in:

  • Direct ortho-arylation of pyridinecarboxylic acids.
  • Catalyzing Suzuki–Miyaura cross-coupling in the synthesis of 1-heteroaryl-3-azabicyclo[3.1.0]hexanes.
  • Palladium-catalyzed carbonylative carboperfluoroalkylation of alkynes.
  • Suzuki–Miyaura coupling reaction of geminal bis(boryl)cyclopropanes in the synthesis of various gem-disubstituted cyclopropanes.
ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

Learn more about ChemBeads products

For larger scale uses, product also available in powdered form (761435)

Other Notes

High-Throughput Reaction Screening with Nanomoles of Solid Reagents Coated on Glass Beads

Versatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput Experimentation

ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand

Legal Information

cataCXium is a registered trademark of Umicore AG & Co. KG

pictograms

Health hazard
GHS08

signalword

Danger

hcodes

H350i

Hazard Classifications

Carc. 1B Inhalation

Storage Class

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk

WGK 3

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Certificates of Analysis (COA)

Lot/Batch Number
MKCR7836

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Articles

ChemBeads: Solid Catalyst Coating on Glass Beads

ChemBeads, catalyst-coated glass beads, dispense solid chemical reagents for nanomole-scale high-throughput reaction screening.

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