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C54007

Chloromethyl methyl sulfide

Name: Chloromethyl methyl sulfide
Brand: ALDRICH

95%

Synonym(s):

Chlorodimethyl sulfide

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About This Item

Linear Formula:

CH₃SCH₂Cl

CAS Number:

2373-51-5

Molecular Weight:

96.58

UNSPSC Code:

12352101

NACRES:

NA.22

PubChem Substance ID:

24892780

EC Number:

219-148-4

Beilstein/REAXYS Number:

1730851

MDL number:

MFCD00000923

Assay:

95%

Form:

liquid

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Properties

Quality Level

100

assay

95%

form

liquid

refractive index

n20/D 1.498 (lit.)

bp

105 °C (lit.)

density

1.153 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

CSCCl

InChI

1S/C2H5ClS/c1-4-2-3/h2H2,1H3

InChI key

JWMLCCRPDOIBAV-UHFFFAOYSA-N

Description

Application

Methylthiomethylating reagent for carbonyl and aromatic compounds. Methylene transfer reagent for iron(II) mediated cyclopropanation.

Disclaimer

May darken in storage.

pictograms

GHS02

signalword

Danger

hcodes

H225

pcodes

P210 - P233 - P240 - P241 - P242 - P243

Hazard Classifications

Flam. Liq. 2

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

62.6 °F - closed cup

flash_point_c

17 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品

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Organic Syntheses, 70, 177-177 (1992)

Insights into the Photodecomposition of Azidomethyl Methyl Sulfide: A S2/S1 Conical Intersection on Nitrene Potential Energy Surfaces Leading to the Formation of S-Methyl-N-sulfenylmethanimine.

Manuel Algarra et al.

The journal of physical chemistry. A, 124(10), 1911-1921 (2020-02-14)

UV photodecomposition of azidomethyl methyl sulfide (AMMS) yields a transient S-methylthiaziridine which rapidly evolves to S-methyl-N-sulfenylmethanimine at 10 K. This species was detected by infrared matrix isolation spectroscopy. The mechanism of the photoreaction of AMMS has been investigated by a

Chemistry Letters (Jpn), 653-653 (1993)

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Global Trade Item Number

SKU	GTIN
C54007-5G	04061837793967
C54007-25G	04061837793950
C54007-100G	04061833502037