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Sigma-Aldrich

AmberChrom™ 1X8 chloride form

chloride form, strongly basic, 200-400 mesh

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Linear Formula:
(C10H12 · C10H10 · C8H8 · C3H9N)X
CAS Number:
69011-19-4
MDL number:
MFCD00132718

Quality Level

200

description

cross-linkage 8%

form

beads

parameter

66 °C OH- form max. temp.

moisture

39-45%

loss

~40% loss on drying, 110 °C

matrix

styrene-divinylbenzene (gel)

particle size

200-400 mesh

operating pH

0-14

capacity

1.2 meq/mL by wetted bed volume

InChI

1S/C10H12.C10H10.C8H8.C3H9N/c2*1-3-9-7-5-6-8-10(9)4-2;1-2-8-6-4-3-5-7-8;1-4(2)3/h3,5-8H,1,4H2,2H3;3-8H,1-2H2;2-7H,1H2;1-3H3

InChI key

HADXLRSCRPYPJJ-UHFFFAOYSA-N

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Application

AmberChrom™ 1X8 chloride form is a strongly basic (type I) anion exchange resin for fine chemical processing. AmberChrom™ has been used to determine trace levels of rhodium and platinum in environmental biological samples.
Strongly basic (type I) anion exchange resin for fine chemical processing; meets requirements of FDA Food Additive Regulation 21 CFR 173.25.

Legal Information

Amberchrom is a trademark of DuPont de Nemours, Inc.

Storage Class Code

10 - Combustible liquids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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  5. How can a Dowex type 1 resin in the chloride form be converted to the carbonate form?

    As one might expect, the procedure requires the use of sodium carbonate (Na2CO3).Citation: Journal of Experimental Medicine, 120, 1007-1018 (1965).From page 1011 of that paper:"A 2 mL column of washed Dowex-1X8 200 to 400 mesh, in the chloride form, was converted to the carbonate form by washing with 1 M Na2CO3 until no chloride could be detected in the eluate. It was then washed with distilled water until the pH of the eluate reached neutrality". The simplest test for chloride is to use a dilute silver nitrate solution. If mixing a few drops of the eluate with a few drops of a silver nitrate solution results in a silver chloride precipitate forming, that would an indication that the eluate contains chloride. You could also use a chloride-specific electrode, if you have access to one.

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P Cañada Rudner et al.
Talanta, 46(5), 1095-1105 (2008-10-31)
1,5-Bis[(2-pyridyl)-3-sulphophenyl methylene] thiocarbonohydrazide (PSTH) immobilized on an anion-exchange resin (Dowex) has been used for the on-line preconcentration of mercury from biological samples and waters prior to its determination by inductively coupled plasma atomic emission spectroscopy. The metal was eluted from
F Sánchez Rojas et al.
Talanta, 64(1), 230-236 (2008-10-31)
A method for the determination of rhodium in different samples at trace levels is presented. The investigated metal is preconcentrated on a chelating resin microcolumn (1,5-bis(2-pyridyl)-3-sulphophenyl methylene thiocarbonohydrazide (PSTH) immobilized on an anion-exchange resin (Dowex 1x8-200)) placed in the autosampler
M M González García et al.
Analytical and bioanalytical chemistry, 375(8), 1229-1233 (2003-05-07)
A method to determine trace amounts of platinum in different samples based on electrothermal atomic absorption spectrometry is described. The preconcentration step is performed on a chelating resin microcolumn [1,5-bis(2-pyridyl)-3-sulfophenyl methylene thiocarbonohydrazide (PSTH) immobilized on an anion-exchange resin (Dowex 1x8-200)]
Connor M Blair et al.
Bio-protocol, 10(7), e3581-e3581 (2021-03-05)
Cyclic nucleotide degrading phosphodiesterase (PDE) enzymes are crucial to the fine tuning of cAMP signaling responses, playing a pivotal role in regulating the temporal and spatial characteristics of discrete cAMP nanodomains and hence the activity of cAMP-effector proteins. As a
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Science (New York, N.Y.), 373(6556) (2021-08-14)
Capturing the heterogeneous phenotypes of microbial populations at relevant spatiotemporal scales is highly challenging. Here, we present par-seqFISH (parallel sequential fluorescence in situ hybridization), a transcriptome-imaging approach that records gene expression and spatial context within microscale assemblies at a single-cell

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