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216224

Sigma-Aldrich

Potassium persulfate

ACS reagent, ≥99.0%

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Synonym(s):
KPS, Potassium peroxodisulfate
Linear Formula:
K2S2O8
CAS Number:
Molecular Weight:
270.32
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.21

grade

ACS reagent

Quality Level

vapor density

9.3 (vs air)

vapor pressure

<0.1 hPa ( 25 °C)

Assay

≥99.0%

form

powder or crystals

reaction suitability

reagent type: catalyst
reaction type: C-H Activation

reagent type: oxidant

impurities

≤0.001% Cl compounds
≤0.005% insolubles

pH

2.5-4.5 (25 °C, 27 g/L)

cation traces

Fe: ≤5 ppm
Mn: ≤2 ppm
heavy metals (as Pb): ≤0.001%

SMILES string

[K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O

InChI

1S/2K.H2O8S2/c;;1-9(2,3)7-8-10(4,5)6/h;;(H,1,2,3)(H,4,5,6)/q2*+1;/p-2

InChI key

USHAGKDGDHPEEY-UHFFFAOYSA-L

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General description

Potassium persulfate is a water-soluble inorganic salt that releases oxygen and exhibits a strongly exothermic reaction. It is stable at room temperature but decomposes at high temperatures. Potassium persulfate is commonly used as an oxidant and in the polymerization of numerous monomers, mainly in the field of hydrogel synthesis.

Application

Potassium persulfate is used as an oxidizing agent:

  • in the oxidation of 4-Chloro-3-methylphenol in pressurized hot water and supercritical water in a continuous flow system.
  • in determinations of dissolved organic carbon.
Potassium persulfate (KPS) has also been used as a redox initiator :

  • in the graft polymerization of acrylonitrile onto starch in aqueous solution.
  • in the synthesis of sulfate radical anions via polymerization processes.
  • as polymerization and radical initiator in the synthesis of polyacrylamide-Laponite-lead dioxide nanoparticle hydrogel composites by acrylamide as monomers.

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Ox. Sol. 3 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

5.1B - Oxidizing hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Information

危险化学品

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Potassium persulfate as oxidant in pressurized hot water
Juhani K, et al.
Environmental Science & Technology, 33, 2095-2099 (1999)
A systematic study of triangular silver nanoplates: one-pot green synthesis, chemical stability, and sensing application
Yosia Nico W, et al.
Nanoscale, 9, 11705-11712 (2017)
Oxidation of 4-chloro-3-methylphenol in pressurized hot water/supercritical water with potassium persulfate as oxidant
Juhani K, et al.
Environmental Science & Technology, 35, 3247-3251 (2001)
UV-initiated bubble-free frontal polymerization in aqueous conditions
Paul Michael P, et al.
Macromolecules, 48, 8738-8745 (2015)
Kinetics and mechanism of graft polymerization of acrylonitrile onto starch initiated with potassium persulfate
zadeh t mt, et al.
Journal of science (2001)

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