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Graphene from sugar and its application in water purification.

ACS applied materials & interfaces (2012-07-14)
Soujit Sen Gupta, Theruvakkattil Sreenivasan Sreeprasad, Shihabudheen Mundampra Maliyekkal, Sarit Kumar Das, Thalappil Pradeep
ABSTRACT

This paper describes a green method for the synthesis of graphenic material from cane sugar, a common disaccharide. A suitable methodology was introduced to immobilize this material on sand without the need of any binder, resulting in a composite, referred to as graphene sand composite (GSC). Raman spectroscopy confirmed that the material is indeed graphenic in nature, having G and D bands at 1597 and 1338 cm(-1), respectively. It effectively removes contaminants from water. Here, we use rhodamine 6G (R6G) as a model dye and chloropyrifos (CP) as a model pesticide to demonstrate this application. The spectroscopic and microscopic analyses coupled with adsorption experiments revealed that physical adsorption plays a dominant role in the adsorption process. Isotherm data in batch experiments show an adsorption capacity of 55 mg/g for R6G and 48 mg/g for CP, which are superior to that of activated carbon. The adsorbent can be easily regenerated using a suitable eluent. This quick and cost-effective technique for the into a commercial water filter with appropriate engineering.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Rhodamine 6G, Dye content 99 %
Sigma-Aldrich
Rhodamine 6G, Dye content ~95 %
Sigma-Aldrich
Rhodamine 6G, suitable for fluorescence, BioReagent
Supelco
Rhodamine 6G, analytical standard