Multinuclear palladium(II) complexes from P-C and P-Cl bond cleavage in (R(P),R(P)/S(P),S(P))-[PdCl2{1,2-(P(t)BuCl)2C2B10H10}].

Multinuclear palladium(II) complexes from P-C and P-Cl bond cleavage in (R(P),R(P)/S(P),S(P))-[PdCl2{1,2-(P(t)BuCl)2C2B10H10}].

Chemical communications (Cambridge, England) (2012-09-13)

Ilham Maulana, Peter Lönnecke, Evamarie Hey-Hawkins

ABSTRACT

Two multinuclear palladium(II) complexes have been isolated as decomposition products resulting from P-Cl and P-C bond cleavage in (R(P),R(P)/S(P),S(P))-[PdCl(2){1,2-(P(t)BuCl)(2)C(2)B(10)H(10)}] in dichloromethane.

MATERIALS

Product Number

Brand

Product Description

270997

Sigma-Aldrich

Dichloromethane, anhydrous, ≥99.8%, contains 40-150 ppm amylene as stabilizer

66742

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439223

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D65100

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650463

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