Skip to Content
Merck
CN
  • Tracking mobility using human hair: What can we learn from lead and strontium isotopes?

Tracking mobility using human hair: What can we learn from lead and strontium isotopes?

Science & justice : journal of the Forensic Science Society (2015-01-13)
Geneviève Vautour, André Poirier, David Widory
ABSTRACT

The isotope ratios of strontium (Sr) and lead (Pb) in water derive from local geology and their isotopic signature can be linked to the age and type of underlying bedrocks and soils (if applicable), and are transferred up the food-chain. Both elements are transferred to human blood through diet and water, and some of it will ultimately be incorporated into the hair structure, making Sr and Pb isotopes interesting tools for tracing human mobility. In this study, we analyzed both the elemental concentration and isotope ratios of Sr and Pb from four different women of different ages to monitor their permanent relocation from central France to Eastern Canada during the summer 2012. For comparison, we also characterized bulk hair samples of sedentary individuals and local tap waters from their regions of origin and of settlement. Our results indicate that the 87Sr/86Sr and 206Pb/204Pb ratios are significantly modified by the change of environment, but also confirm that human hair compositions are impacted by other external factors (such as dust). Sr and Pb isotope systematics demonstrate their added value for detecting human mobility, but require further studies to better constrain the main sources and processes controlling their respective budgets in human hair for provenancing purposes.

MATERIALS
Product Number
Brand
Product Description

Supelco
Hydrochloric acid solution, volumetric, 0.1 M HCl (0.1N), endotoxin free
Supelco
Hydrogen chloride – ethanol, ~1.25 M HCl, derivatization grade (GC derivatization), LiChropur
Supelco
Hydrogen chloride – 2-propanol solution, ~1.25 M HCl (T), derivatization grade (GC derivatization), LiChropur
Supelco
Hydrogen chloride – methanol solution, ~1.25 m HCl (T), derivatization grade (GC derivatization), LiChropur
Sigma-Aldrich
Nitric-14N acid solution, ~10 N in H2O, 99.99 atom % 14N
Sigma-Aldrich
Methanol, suitable for HPLC, gradient grade, ≥99.9%
Supelco
Methanol, Pharmaceutical Secondary Standard; Certified Reference Material
Supelco
Methanol, analytical standard
Sigma-Aldrich
Chloroform, contains ethanol as stabilizer, ACS reagent, ≥99.8%
Sigma-Aldrich
Methanol, suitable for HPLC, gradient grade, suitable as ACS-grade LC reagent, ≥99.9%
Sigma-Aldrich
Chloroform, contains amylenes as stabilizer, ACS reagent, ≥99.8%
Sigma-Aldrich
Chloroform, anhydrous, ≥99%, contains 0.5-1.0% ethanol as stabilizer
Sigma-Aldrich
Chloroform, ACS spectrophotometric grade, ≥99.8%, contains 0.5-1.0% ethanol as stabilizer
Sigma-Aldrich
Chloroform, contains 100-200 ppm amylenes as stabilizer, ≥99.5%
Sigma-Aldrich
Chloroform, anhydrous, contains amylenes as stabilizer, ≥99%
Supelco
Chloroform, analytical standard
Supelco
Chloroform, Pharmaceutical Secondary Standard; Certified Reference Material
Sigma-Aldrich
Chloroform, ≥99%, PCR Reagent, contains amylenes as stabilizer
Sigma-Aldrich
Methanol, ACS reagent, ≥99.8%
Sigma-Aldrich
Hydrogen chloride solution, 1.0 M in acetic acid
Sigma-Aldrich
Hydrochloric acid, ACS reagent, 37%
Sigma-Aldrich
Hydrochloric acid, puriss., 24.5-26.0%
Sigma-Aldrich
Hydrochloric acid, meets analytical specification of Ph. Eur., BP, NF, fuming, 36.5-38%
Sigma-Aldrich
Hydrochloric acid solution, for amino acid analysis, ~6 M in H2O
Sigma-Aldrich
Hydrochloric acid, ACS reagent, 37%
Sigma-Aldrich
Hydrochloric acid solution, 1.0 N, BioReagent, suitable for cell culture
Sigma-Aldrich
Hydrochloric acid, 37 wt. % in H2O, 99.999% trace metals basis
Sigma-Aldrich
Hydrochloric acid, puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., fuming, ≥37%, APHA: ≤10
Sigma-Aldrich
Hydrochloric acid, 36.5-38.0%, BioReagent, Molecular Biology
Sigma-Aldrich
Methanol, ACS reagent, ≥99.8%