205036
三(三苯基膦)氯化铑(I)
99.9% trace metals basis
别名:
NSC 124140, RhCl (PPh 3 ) 3, Wilkinson 催化剂, 三(三苯膦基)氯化铑(I)
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关于此项目
线性分子式:
[(C6H5)3P]3RhCl
化学文摘社编号:
分子量:
925.22
UNSPSC Code:
12161600
NACRES:
NA.22
PubChem Substance ID:
EC Number:
238-744-5
Beilstein/REAXYS Number:
4581440
MDL number:
Quality Level
assay
99.9% trace metals basis
reaction suitability
core: rhodium, reagent type: catalyst
SMILES string
Cl[Rh].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9
InChI
1S/3C18H15P.ClH.Rh/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;1H;/q;;;;+1/p-1
InChI key
IXAYKDDZKIZSPV-UHFFFAOYSA-M
Application
用于芳基硼酸与活化的烯基甲苯磺酸酯进行交叉偶联反应的有效催化剂。也用于催化 DABCO 作用下烯丙基酚醚裂解为酚。
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ppe
Eyeshields, Gloves, type N95 (US)
flash_point_f
Not applicable
flash_point_c
Not applicable
hcodes
pcodes
Hazard Classifications
Aquatic Chronic 2
存储类别
13 - Non Combustible Solids
商品
Discover the role of boronic acids in enantioenriched C(sp2)–C(sp2) product synthesis, specifically the rhodium-catalyzed Suzuki–Miyaura-type arylations of allylic halides and cyclobutenes.
European Journal of Organic Chemistry, 5260-5260 (2006)
Sonsoles Rodriguez Aristegui et al.
Organic letters, 8(26), 5927-5929 (2006-12-15)
[Structure: see text] 2-morpholin-4-yl-4-oxo-4H-chromen-8-yl 2,2,2-trifluoromethanesulfonate is a key intermediate for the synthesis of the DNA-dependent protein kinase (DNA-PK) inhibitor 8-dibenzothiophen-4-yl-2-morpholin-4-yl-chromen-4-one (NU7441). Two improved methods for the synthesis of this triflate have been developed: (A) in 35% overall yield, through modification
P Andrew Evans et al.
Journal of the American Chemical Society, 124(30), 8782-8783 (2002-07-26)
Transition metal-catalyzed cycloaddition reactions represent powerful methods for the construction of complex polycyclic systems. We have developed a new intermolecular metal-catalyzed [4 + 2 + 2] cycloaddition of heteroatom-tethered enyne derivatives with 1,3-butadiene. This study demonstrates that excellent selectivity can
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 205036-1G | 04061838767431 |
| 205036-250MG | 04061833481974 |
| 205036-5G | 04061838767448 |