683167
氯降冰片二烯铑二聚体
Umicore, powder
别名:
[Rh(nbd)Cl]2, 二氯化二铑(双降冰片二烯), 氯化降冰片二烯铑二聚物, 降冰片二烯氯化铑二聚体
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关于此项目
经验公式（希尔记法）:
C14H16Cl2Rh2
化学文摘社编号:
分子量:
460.99
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
235-510-4
MDL number:
产品名称
氯降冰片二烯铑二聚体, Umicore
InChI
1S/2C7H8.2ClH.2Rh/c2*1-2-7-4-3-6(1)5-7;;;;/h2*1-4,6-7H,5H2;2*1H;;/q;;;;2*+1/p-2/t2*6-,7+;;;;
InChI key
RXDWVIOULPVOEO-SEGRDSFWSA-L
SMILES string
Cl[Rh].Cl[Rh].[CH]1[CH]C2[CH][CH]C1C2.[CH]3[CH]C4[CH][CH]C3C4
form
powder
reaction suitability
core: rhodium, reagent type: catalyst
Quality Level
Application
Catalyst for valence isomerization and N-heterocyclization; incombination with phosphorus ligands are catalysts for hydrogenationof many functional groups and hydroformylation; withchiral ligands are catalysts for asymmetric hydrogenation
Legal Information
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Becalski, A. G.; Cullen,W. R. et al.
Inorganic Chemistry, 30, 5002-5002 (1991)
Tani, K.; Tanigawa, E.; Tatsuno, Y.; Otsuka, S.
Journal of Organometallic Chemistry, 279, 87-87 (1985)
Taylor, R. B.; Jennings, P. W.
Inorganic Chemistry, 20, 3997-3997 (1981)
Watanabe, Y.; Shim, S. C.; Mitsudo, T.
Bulletin of the Chemical Society of Japan, 54, 3460-3460 (1981)
商品
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