900943
Chloro(4-cyanophenyl)[(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine]nickel(II)
powder or solid
Synonym(s):
SK-J003-1n
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About This Item
Empirical Formula (Hill Notation):
C43H60ClFeNNiP2
CAS Number:
Molecular Weight:
802.88
MDL number:
UNSPSC Code:
12352103
NACRES:
NA.22
Product Name
Chloro(4-cyanophenyl)[(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine]nickel(II),
form
powder or solid
Quality Segment
reaction suitability
core: nickel, reaction type: Cross Couplings, reagent type: catalyst
reaction type: Asymmetric synthesis
SMILES string
Cl[Ni+2]C1=CC=C(C#N)C=C1.C[C@@H](P(C2CCCCC2)C3CCCCC3)[C]4[C][C][C][C]4P(C5CCCCC5)C6CCCCC6.[C]7[C][C][C][C]7.[Fe]
Application
Amination of aryl chlorides, bromides and sulfonates with ammonia. Amination of aryl carbamates with ammonia or ammonium salts.
signalword
Warning
hcodes
Hazard Classifications
Aquatic Chronic 2 - Repr. 2 - Skin Irrit. 2
Storage Class
4.1B - Flammable solid hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Evaluating 1, 1?-Bis (phosphino) ferrocene Ancillary Ligand Variants in the Nickel-Catalyzed C?N Cross-Coupling of (Hetero) aryl Chlorides.
Clark J S, et al.
Organometallics, 36(3), 679-686 (2017)
Nickel?Catalyzed Monoarylation of Ammonia.
Borzenko A, et al.
Angewandte Chemie (International Edition in English), 54(12), 3773-3777 (2015)
Ni?Catalyzed Amination Reactions: An Overview.
Marin M, et al.
Chemical Record, 16(4), 1819-1832 (2016)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 900943-250MG | 04061833315309 |